Phosphor Storage Screen Epoxy Treatment for Iodine Yellowing

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Solution Overview

Problem

Phosphor storage screens used in medical radiography undergo yellowing due to iodine oxidation, leading to unsightly appearance and compromised image quality during digitization, especially in dental applications where screens are exposed to UV light and humidity.

Innovation Solution

Treating phosphor screens with a gaseous epoxy compound, such as oxirane, during or after production to prevent iodine yellowing by allowing epoxy molecules to interact with phosphor particles, thereby forming a protective layer that inhibits iodine gas absorption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If phosphor screens contain iodine for radiographic use, then the phosphor can store latent images effectively, but yellowing occurs due to iodine oxidation leading to poor image quality

Engineering Contradiction:
Improvelatent image storage capabilityVSAvoidyellowing and image degradation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

An epoxy-containing compound is introduced as an intermediary substance between the iodine-containing phosphor and the environment. This compound reacts with iodine to form a protective layer that prevents iodine oxidation and subsequent yellowing, while allowing the phosphor to maintain its latent image storage function

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The epoxy compound reacts with the potentially harmful iodine that causes yellowing, converting this harmful element into a stable complex. The reaction product forms a protective layer that actually benefits the screen by preventing further degradation while preserving the phosphor's imaging capabilities

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Adaptability or versatility

If screens are exposed to UV light and humidity for dental applications, then the screens can be used in various environments, but yellowing accelerates due to iodine oxidation

Engineering Contradiction:
Improveenvironmental adaptabilityVSAvoidscreen lifespan and image quality
Core Design Contradiction:
Adaptability or versatilityVSDuration of action of stationary object

Solution Approach 1:

The epoxy compound is applied in advance to create a protective barrier against UV light and humidity. This preliminary action prevents the harmful interaction between environmental factors and iodine before oxidation can occur, thereby extending the screen's usable life in diverse environments

Inventive Principle:
Principle #9Preliminary anti-action

3Object-affected harmful factors

If epoxy compound is applied to phosphor screens, then yellowing is prevented, but additional processing steps are required

Engineering Contradiction:
Improveyellowing preventionVSAvoidproduction process complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The epoxy-containing compound is applied during the phosphor screen production process itself, before the screen is put into service. This preliminary action ensures the protective function is built-in from the start, avoiding the need for separate post-production treatment steps

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Prevents yellowing and maintains image quality by ensuring the epoxy compound effectively reacts with iodine, reducing the risk of iodine gas absorption and enhancing the stability and safety of the screens.

Implementation Method 1

a treatment with at least an epoxy group containing compound in gaseous form is applied to said phosphorous composition

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

allowing epoxy molecules to interact with phosphor particles, thereby forming a protective layer that inhibits iodine gas absorption

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

In the case of oxirane, it is thought that probably the triangle opens up and interacts with the surface of the phosphor particle

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 4

a yellowing of the screens occur. The probable cause of this phenomenon is that iodine, present for e.g. 15 mol %, is available for oxidation at the surface of the grain and as a result is converted to iodine gas

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS9326741B2Storage screens for medical radiography
Publication Date: 2016.05.03 AGFA NV
  • US9326741B2 patent drawing

AI summary

The present invention concerns a method for the treatment of stimulable phosphors and/or screens for use in diagnosis, in particular medical radiography. The method comprises subjecting the stimulable phosphors and/or screens to an epoxide containing gaseous compound, promptly following their manufacture. By applying the method according to the invention yellowing of the stimulable phosphors and/or screens is prevented in a safe and efficient manner; thereby the disadvantages known as such resulting from such yellowing will not occur.