Phosphor-TiO2 Hybrid Filter Media for Visible-Light Photolysis

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Solution Overview

Problem

Titanium dioxide photocatalysts require high-energy ultraviolet light for activation, limiting their efficiency in sunlight and nano-sized particles pose application challenges in air purification systems.

Innovation Solution

A phosphor-transition metal-photocatalyst hybrid composite material is developed, using phosphor beads as a support for nano-sized titanium dioxide, coated with a photocatalyst and transition metal, enabling activation by both UV and visible light, and promoting photolysis even in dark environments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If titanium dioxide photocatalyst is used, then strong photolysis performance is achieved, but photo-activation is limited to ultraviolet light only

Engineering Contradiction:
Improvephotolysis performanceVSAvoidlight absorption range
Core Design Contradiction:
PowerVSAdaptability or versatility

Solution Approach 1:

The patent combines titanium dioxide photocatalyst particles with phosphor particles to create a composite material. The phosphor component absorbs visible light and converts it to ultraviolet light through down-conversion, enabling the TiO2 photocatalyst to be activated by visible light in addition to UV light, thereby expanding the light absorption range while maintaining strong photolysis performance

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The phosphor acts as an intermediary substance that mediates between visible light and the titanium dioxide photocatalyst. It absorbs visible light photons and converts them to UV light photons that can activate the TiO2, serving as a bridge that enables indirect photo-activation by visible light

Inventive Principle:
Principle #24Intermediary (Mediator)

2Power

If nano-sized titanium dioxide particles are used, then photoactive reaction is enhanced, but direct application in devices becomes difficult

Engineering Contradiction:
Improvephotoactive reactionVSAvoiddevice application
Core Design Contradiction:
PowerVSEase of manufacture

Solution Approach 1:

The patent merges the nano-sized titanium dioxide photocatalyst particles with phosphor particles into a single composite structure. The TiO2 nanoparticles are coated on or combined with the phosphor particles, allowing the nano-sized photocatalyst to be handled and applied as larger composite particles that are easier to manufacture and install in air purification devices

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent creates a hierarchical structure where nano-sized TiO2 particles are localized on the surface of larger phosphor particles. This local concentration of photocatalyst material on the phosphor surface maintains high photoactive reaction capability while the overall composite particle size enables practical device application

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite material enhances photolysis efficiency, allowing effective air purification in various lighting conditions and facilitating easy integration into air purification systems.

Implementation Method 1

a phosphor material, and wherein the photocatalyst layer is formed on the surface of each of the plurality of beads supporting the plurality of transition metal particles

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Implementation Method 2

generates radicals with strong oxidizing power when exposed to ultraviolet light, and the radicals decompose various environmental pollutants present in water or air into harmless carbon dioxide, water, etc.

Methodology Applied
Scientific EffectPhotolysis: Photodissociation

Implementation Method 3

Titanium dioxide (TiO2), known as a representative photocatalyst material, generates radicals with strong oxidizing power when exposed to ultraviolet light

Methodology Applied
Scientific EffectPhoto-oxidation: Photo-oxidation

Data Source

PatentUS12623209B2Phosphor-transition metal-photocatalyst hybrid composite material, method for preparing the same, and filter using the same
Publication Date: 2026.05.12 HYUNDAI MOTOR CO LTD
  • US12623209B2 patent drawing
  • US12623209B2 patent drawing
  • US12623209B2 patent drawing

AI summary

A phosphor-transition metal-photocatalyst hybrid composite material includes a plurality of beads including a phosphor material, a binder, and zeolite, a plurality of transition metal particles supported on the surface of each of the plurality of beads, and a photocatalyst layer formed on the surface of each of the plurality of beads supporting the transition metal particles by coating a photocatalyst material.