Phosphoric Acid Storage Tank Heating for Etchant Concentration Control

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The concentration of silicon in etching liquids used for substrate processing systems can become excessive, leading to silicon oxide deposition on silicon oxide films, inhibiting the etching process, and the concentration of phosphoric acid can decrease due to moisture absorption, affecting the etching process's effectiveness.

Innovation Solution

A storage device with a heating mechanism and controller is used to maintain the concentration of phosphoric acid by adjusting the temperature to balance evaporation and absorption, and a deposition preventing/reducing agent is added to the etching liquid to prevent silicon oxide deposition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If the processing liquid is stored at room temperature, then the operation is simple, but the phosphoric acid concentration decreases due to moisture absorption

Engineering Contradiction:
Improvestorage operation simplicityVSAvoidphosphoric acid concentration stability
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent applies parameter changes by controlling the temperature of the processing liquid to maintain a specific range (5°C to 40°C, preferably 10°C to 30°C). This temperature control parameter change balances moisture absorption and evaporation rates, preventing concentration deviation without requiring complex operational procedures. The heating mechanism enables this parameter control while keeping the system relatively simple.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If the temperature is increased to reduce moisture absorption, then the concentration stability improves, but the energy consumption increases

Engineering Contradiction:
Improveprocessing liquid concentration stabilityVSAvoidheating energy consumption
Core Design Contradiction:
Stability of the object's compositionVSUse of energy by moving object

Solution Approach 1:

The patent applies partial action by heating the processing liquid only to a moderate temperature range (5°C to 40°C, preferably 10°C to 30°C) rather than to high temperatures. This partial heating is sufficient to reduce moisture absorption while avoiding excessive energy consumption. The system does not require continuous high-temperature maintenance, making the energy input moderate and efficient.

Inventive Principle:
Principle #16Partial or excessive action

Solution Approach 2:

The patent optimizes the temperature parameter to balance concentration stability and energy consumption. By maintaining temperature within a specific range rather than using extreme values, the system achieves adequate concentration control with moderate energy input. The heating mechanism provides flexible parameter adjustment to match actual operational needs.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If no temperature control is applied, then the device complexity is low, but the etching process becomes ineffective due to concentration decrease

Engineering Contradiction:
Improvetemperature control mechanism complexityVSAvoidetching process effectiveness
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent implements a relatively simple temperature control mechanism that maintains the processing liquid within a specific temperature range (5°C to 40°C). This parameter control is sufficient to prevent concentration deviation and ensure etching effectiveness without requiring complex multi-component systems. The heating mechanism provides the necessary control with minimal added complexity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a feedback control system where the controller monitors the temperature of the processing liquid and adjusts the heating mechanism accordingly. This feedback loop ensures the temperature remains within the optimal range, maintaining concentration stability and etching effectiveness. The feedback mechanism is implemented in a straightforward manner, adding minimal complexity while significantly improving reliability.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution ensures stable etching performance by maintaining the concentration of phosphoric acid and preventing silicon oxide deposition, thereby ensuring proper etching processes.

Implementation Method 1

The heating mechanism heats the processing liquid that is stored in the storage tank

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 2

a temperature of the processing liquid is adjusted in such a manner that an amount of evaporation of water for the processing liquid

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

an amount of absorption of moisture for the processing liquid in the storage tank

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS12615696B2Storage device and storage method
Publication Date: 2026.04.28 TOKYO ELECTRON LTD
  • US12615696B2 patent drawing
  • US12615696B2 patent drawing
  • US12615696B2 patent drawing

AI summary

A storage device according to an aspect of the present disclosure includes a storage tank, a heating mechanism, and a controller. The storage tank stores a processing liquid that contains an aqueous solution of phosphoric acid and an additive. The heating mechanism heats the processing liquid that is stored in the storage tank. The controller controls the heating mechanism to execute a concentration maintaining process where a temperature of the processing liquid is adjusted in such a manner that an amount of evaporation of water for the processing liquid in the storage tank approaches an amount of absorption of moisture for the processing liquid in the storage tank.