Photo Cathode Carbon Bonding Layer Ion Feedback

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Solution Overview

Problem

Existing photo cathodes with negative electron affinity (NEA) suffer from low quantum efficiency due to weak bonding between the III-V based cathode layer and electron exit layer, which makes them vulnerable to chemical attacks and ion feedback, leading to reduced signal output and shorter device lifespan.

Innovation Solution

A carbon-containing layer is introduced between the photo cathode layer and the electron exit layer to create a strong chemical bond, eliminating the need for an ion barrier membrane and enhancing the cathode's resistance to chemical attacks and ion feedback, while maintaining high quantum efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If an electron exit layer is deposited on the photo cathode layer to improve quantum efficiency, then the quantum efficiency increases, but the bonding between the cathode layer and electron exit layer becomes weak due to Van der Waals forces

Engineering Contradiction:
Improvequantum efficiencyVSAvoidbonding strength
Core Design Contradiction:
Measurement precisionVSStrength

Solution Approach 1:

A carbon-containing layer is introduced as an intermediary between the photo cathode layer and the electron exit layer. This intermediate layer forms strong chemical bonds (covalent or ionic) with both adjacent layers, replacing the weak Van der Waals forces with robust chemical bonding while preserving the high quantum efficiency provided by the electron exit layer.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The cathode structure is designed as a composite material system consisting of three distinct layers: the photo cathode layer (e.g., III-V semiconductor), the carbon-containing intermediate layer, and the electron exit layer (e.g., alkali metal compound). This composite structure combines the advantages of each material while mitigating their individual weaknesses, particularly the weak bonding issue.

Inventive Principle:
Principle #40Composite materials

2Reliability

If an ion barrier membrane is introduced to protect the electron exit layer from ion feedback, then the protection against ion feedback improves, but the quantum efficiency decreases due to reduced primary electron transmission

Engineering Contradiction:
Improveresistance to ion feedbackVSAvoidquantum efficiency
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

The ion barrier membrane, which causes the harmful side effect of reduced quantum efficiency, is completely removed from the structure. Instead, the carbon-containing layer itself provides protection against ion feedback through its strong bonding and resistance to chemical attacks, eliminating the need for a separate protective membrane.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The carbon-containing layer is designed to perform multiple functions simultaneously: it provides strong chemical bonding between the photo cathode layer and electron exit layer, protects against chemical attacks from gasses, and resists ion feedback. This multi-functional design eliminates the need for separate protective components that would compromise quantum efficiency.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Duration of action of stationary object

If the electron exit layer is protected from chemical attacks, then the lifespan increases, but the device complexity increases due to additional protective structures

Engineering Contradiction:
ImprovelifespanVSAvoidstructure complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The carbon-containing layer serves multiple protective and bonding functions within a single component, eliminating the need for additional protective structures. It provides chemical bonding, resistance to chemical attacks from gasses and phosphor screens, and protection against ion feedback, thereby extending lifespan without increasing device complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The strong bonding between the carbon-containing layer and the electron exit layer increases the cathode's resistance to chemical attacks and ion feedback, resulting in a longer lifespan and higher quantum efficiency without the need for an ion barrier membrane, thereby improving the overall performance of the photo cathode.

Implementation Method 1

a cathode which under the influence of incident radiation, such as light or X-rays or other elementary particles (electrons), emits electrons, like for example photo electrons

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Implementation Method 2

Some other materials have a negative electron affinity (NEA). In materials with a NEA the electron gains energy upon entering the vacuum, therefore the chance of being emitted to the vacuum is fairly high

Methodology Applied
Scientific EffectNegative electron affinity:

Implementation Method 3

A carbon-containing layer is introduced between the photo cathode layer and the electron exit layer to create a strong chemical bond

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Data Source

PatentEP2545578B1A photo cathode for use in a vacuum tube as well as such a vacuum tube
Publication Date: 2016.03.09 PHOTONIS FRANCE
  • EP2545578B1 patent drawingFigure 1
  • EP2545578B1 patent drawingFigure 2
  • EP2545578B1 patent drawingFigure 3

AI summary

The invention relates to a photo cathode for use in a vacuum tube at least comprising a cathode layer, having an entrance face capable for absorbing photons impinging on said cathode layer, and an exit face for releasing electrons upon impinging of said photons; as well as an electron exit layer, in facing relationship with said exit face of said cathode layer for improving said releasing of said electrons; and a carbon containing layer, positioned between said exit face of said cathode layer and said electron exit layer, for bonding said electron exit layer to said cathode layer. The invention also relates to a vacuum tube using such a photo cathode.