Photo-reactive Planarization via Solubility Control

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Solution Overview

Problem

Chemical Mechanical Polishing (CMP) is a harsh and expensive process that cannot be used for certain microfabrication steps, such as transistor fabrication, and reduces the yield of functional integrated circuits due to its abrasive nature and limitations in planarization.

Innovation Solution

A chemical-based planarization process using photo-reactive generator compounds that generate solubility-changing agents in response to actinic radiation, allowing for selective and differential material removal across a substrate without mechanical polishing, utilizing a digital pixel-based or mask-based projection system to control the z-height adjustments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If Chemical Mechanical Polishing (CMP) is used for planarization, then a planar surface can be achieved, but the process becomes harsh, expensive, and reduces yield due to abrasive nature

Engineering Contradiction:
Improvesurface planarityVSAvoidabrasive damage and process harshness
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent replaces the mechanical polishing component of CMP with a purely chemical process. A photoresist layer is deposited and selectively removed through photolithographic exposure and development, dissolving material chemically rather than mechanically. This substitution eliminates abrasive damage while achieving the desired planarization and pattern transfer.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental mechanism from mechanical-chemical (CMP) to purely chemical (photolithographic dissolution). By controlling exposure dose, photoresist formulation, and development conditions, the process achieves precise material removal without mechanical contact, transforming the planarization approach from abrasive to selective chemical etching.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If CMP is used for planarization, then insulators and conductors can be planarized, but the process cannot be used for transistor fabrication and front-end-of-line structures

Engineering Contradiction:
Improvematerial compatibilityVSAvoiddamage to sensitive structures
Core Design Contradiction:
Adaptability or versatilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies selective planarization by controlling the photolithographic exposure pattern. Different regions receive different exposure doses, causing selective dissolution of the photoresist layer. This allows precise control over which areas are planarized and which are protected, enabling safe processing of sensitive transistor structures while still achieving planarization where needed.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

By replacing mechanical polishing with selective chemical dissolution controlled by photolithographic patterning, the process becomes compatible with sensitive front-end-of-line structures. The chemical process can be precisely controlled to protect gate oxides and other delicate features while still achieving the required planarization for subsequent processing steps.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If CMP is used for planarization, then the wafer can be prepared for photolithographic patterning, but the process is very expensive and reduces yield

Engineering Contradiction:
Improveplanarization qualityVSAvoidcost and yield
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent replaces expensive mechanical CMP equipment and consumables (polishing pads, slurries) with standard photolithographic tools and photoresist materials. This substitution significantly reduces equipment cost, material cost, and process complexity while maintaining or improving planarization quality through selective chemical removal.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent combines planarization and patterning into a single photolithographic process flow. The same photoresist layer and exposure system used for patterning also perform the planarization function through selective dissolution. This multi-functionality eliminates the need for separate CMP equipment and processes, reducing overall manufacturing cost and simplifying the production line.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method provides a non-abrasive, finely controllable planarization process that can be used for various microfabrication steps, including stacked die parts and high topography configurations, increasing yield and reducing costs compared to traditional CMP methods.

Implementation Method 1

A generator compound is deposited on the filler layer. The generator compound is a compound that generates a solubility-changing agent in response to receiving actinic radiation exposure.

Methodology Applied
Scientific EffectPhoto-reactive generation: Photopolymerisation

Implementation Method 2

The solubility-changing agent is caused to diffuse into at least a portion of the filler layer such that the solubility-changing agent changes a solubility of a top portion of the filler layer.

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS10338466B2System and method for planarizing a substrate
Publication Date: 2019.07.02 TOKYO ELECTRON LTD
  • US10338466B2 patent drawing
  • US10338466B2 patent drawing
  • US10338466B2 patent drawing

AI summary

Techniques include providing selective or differential planarization such that different regions of a substrate can have different amounts of material removed. In general, methods herein use photo-reactive generator compounds to generate solubility-changing agents. A specific pattern of light is projected onto a substrate containing such photo-reactive generator compounds to create different concentrations of solubility-changing agent(s) at specific locations across a substrate. As generated solubility-changing agents are diffused into an underlying layer, these concentration differences then control an amount (height or depth) of material removed from a given film or layer at specific spatial locations on the substrate.