Photoaligning Polymer Materials for Liquid Crystal Orientation

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Solution Overview

Problem

There is a need for advanced photoaligning polymer materials that enable efficient liquid crystal orientation with improved optical properties, compatibility with various solvents, and flexibility in manufacturing processes, particularly for roll-to-roll processes, while requiring less energy and offering superior adhesion to different substrates.

Innovation Solution

The development of novel photoaligning polymer materials with specific repeating structural units, allowing for high compatibility with solvents and substrates, and the use of these materials in orientation layers for liquid crystals, which can be applied at room temperature and used in multi-layer systems for optical and electro-optical elements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional photoaligning polymer materials are used, then liquid crystal orientation can be achieved, but energy consumption is high and manufacturing efficiency is reduced

Engineering Contradiction:
Improveenergy consumptionVSAvoidmanufacturing efficiency
Core Design Contradiction:
Use of energy by moving objectVSProductivity

Solution Approach 1:

The patent modifies the chemical structure of photoaligning polymer materials by introducing specific repeating units with formulas (I) and (II), containing photoaligning groups such as cinnamates, chalcones, coumarins, quinolones, stilbenes, cyanostilbenes, azo groups, chromones, chromenes, mono- and di-acetylene groups, and benzylidenephtalimide groups. These structural parameter changes enable the materials to achieve effective liquid crystal orientation at lower energy levels while maintaining or improving manufacturing efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite photoaligning polymer materials comprising multiple types of repeating structural units with different functions. The copolymer structure combines photoaligning units with spacer units and hydrophobic/hydrophilic balance units, creating a composite material that optimizes both energy efficiency and manufacturing performance through synergistic effects of different molecular components

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If advanced photoaligning materials are developed for efficient manufacturing, then manufacturing precision and optical properties improve, but material complexity increases

Engineering Contradiction:
Improveliquid crystal orientation qualityVSAvoidmaterial structure complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent segments the photoaligning polymer material into distinct functional repeating units: photoaligning groups (formulas I and II), spacer units (S1, S1′) with specific structures, and hydrophobic/hydrophilic balance units. Each segment performs a specific function, allowing the complex material to be designed and optimized systematically while maintaining overall performance

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The repeating structural units in the patent are designed to perform multiple functions simultaneously: photoalignment, spacing, and hydrophobic/hydrophilic balance. This multi-functionality reduces the need for separate additive components, simplifying the overall material system while achieving high manufacturing precision and optical properties

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Ease of operation

If photoaligning materials are applied at elevated temperatures, then coating process flexibility improves, but temperature-sensitive substrates are damaged

Engineering Contradiction:
Improvecoating process flexibilityVSAvoidsubstrate thermal damage
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The photoaligning polymer materials in the patent are designed with inherent properties that enable them to be applied at room temperature without requiring external heating. The materials self-adjust their viscosity and coating characteristics at ambient conditions, eliminating the need for thermal processing and protecting temperature-sensitive substrates from damage

Inventive Principle:
Principle #25Self-service

4Adaptability or versatility

If photoaligning materials with high solvent compatibility are used, then coating method flexibility improves, but adhesion to certain substrates may be compromised

Engineering Contradiction:
Improvesolvent compatibilityVSAvoidsubstrate adhesion
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

The patent introduces local hydrophobic and hydrophilic regions within the polymer chains through specific repeating units. This local quality variation allows the material to interact with different solvents and substrates selectively, maintaining high solvent compatibility while ensuring strong adhesion to diverse substrates through localized molecular interactions

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These materials provide excellent liquid crystal orientation, maintain good optical contrast, and allow for efficient manufacturing processes, including roll-to-roll processes, with reduced energy consumption and enhanced adhesion, enabling a wide range of applications in optical and electro-optical elements.

Implementation Method 1

irradiating the photoaligning polymer material with UV light

Methodology Applied
Scientific EffectUV absorption: Absorption (EM radiation)

Implementation Method 2

The photoaligning polymer materials according to the present invention are very well suited for roll-to-roll processes

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS11874563B2Photoaligning polymer materials
Publication Date: 2024.01.16 ROLIC TECHNOLOGIES AG
  • US11874563B2 patent drawing
  • US11874563B2 patent drawing
  • US11874563B2 patent drawing

AI summary

The present invention relates to novel photoaligning polymer materials, to their use as orienting layer for liquid crystals, which are used for the production of non-structured and structured optical elements, electro-optical elements, multi-layer systems or in nanoelectronics.