Liquid Crystal Photoalignment Agent Copolymer for Uniform Alignment

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Solution Overview

Problem

Existing liquid crystal display technologies face challenges in achieving uniform liquid crystal alignment due to issues like fine dust and static electricity in rubbing methods, leading to suboptimal image quality and afterimages.

Innovation Solution

A liquid crystal photoalignment agent is developed, comprising a copolymer of cyclobutanedianhydride, diamine, and a compound with a flexible structure, which is applied and irradiated with polarized light to form alignment layers, enhancing anisotropy and decomposition efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a rubbing method is used to align liquid crystals, then liquid crystal alignment can be achieved, but fine dust and static electricity occur causing manufacturing problems

Engineering Contradiction:
Improveliquid crystal alignment uniformityVSAvoidfine dust and static electricity
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent replaces the mechanical rubbing method with a photoalignment method using light irradiation. The polymer layer is treated with polarized light to create anisotropic alignment without physical contact, thereby eliminating dust generation and static electricity while achieving uniform liquid crystal alignment.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes photoinduced phase transition in the polymer layer. Upon irradiation with polarized light, the polymer undergoes a phase change that creates anisotropic refractive index, enabling liquid crystal alignment without mechanical rubbing. This phase transition mechanism eliminates the harmful effects of the rubbing method.

Inventive Principle:
Principle #36Phase transitions

2Object-generated harmful factors

If a photoalignment method is used to eliminate dust and static electricity, then manufacturing quality improves, but alignment uniformity and decomposition efficiency need enhancement

Engineering Contradiction:
Improvefine dust and static electricityVSAvoidalignment uniformity
Core Design Contradiction:
Object-generated harmful factorsVSManufacturing precision

Solution Approach 1:

The patent employs a composite polymer layer comprising multiple components: a first polymer providing basic alignment, a second polymer enhancing anisotropy, and a third polymer improving decomposition efficiency. This composite structure achieves superior alignment uniformity and eliminates the trade-off between eliminating harmful factors and maintaining precision.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes multiple parameters including the molecular structure of polymer components, their weight ratios, irradiation light intensity and wavelength, and heat treatment temperature. By systematically adjusting these parameters, the patent achieves both elimination of harmful factors and enhancement of alignment uniformity.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional photoalignment agents are used, then manufacturing is simplified, but afterimage problems persist due to insufficient decomposition efficiency

Engineering Contradiction:
Improvephotoalignment process simplicityVSAvoidafterimage reduction
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent introduces a composite photoalignment agent system with three different polymer components, each contributing specific functions. The third polymer component specifically enhances decomposition efficiency under light irradiation, enabling complete photoalignment without afterimages while maintaining manufacturing simplicity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs a two-stage treatment process: first, irradiation with polarized light to create initial alignment; second, heat treatment to complete the alignment and eliminate afterimages. This periodic action ensures complete decomposition and alignment without compromising manufacturing simplicity.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution improves the alignment uniformity and reduces afterimages by increasing the anisotropy and decomposition efficiency of the liquid crystal photoalignment agent, resulting in better image quality and reduced manufacturing defects.

Implementation Method 1

a photoalignment method where anisotropy is induced to the polymer layer by irradiation of light and the liquid crystals are arranged by using anisotropy

Methodology Applied
Scientific EffectPhotoalignment: Photopolymerisation

Implementation Method 2

irradiation of light and the liquid crystals are arranged by using anisotropy

Methodology Applied
Scientific EffectAnisotropy induction: Anisotropy

Implementation Method 3

a liquid crystal photoalignment agent having excellent anisotropy and decomposition efficiency

Methodology Applied
Scientific EffectPhotodecomposition: Photodissociation

Data Source

PatentUS9857634B2Liquid crystal photoalignment agent, liquid crystal display including the same, and method of manufacturing the same
Publication Date: 2018.01.02 SAMSUNG DISPLAY CO LTD
  • US9857634B2 patent drawing
  • US9857634B2 patent drawing
  • US9857634B2 patent drawing

AI summary

A liquid crystal display includes a first substrate, a thin film transistor positioned on the first substrate, a first electrode connected to the thin film transistor, a second substrate facing the first substrate, a first alignment layer positioned on the first electrode and a second alignment layer positioned on the second substrate, and a liquid crystal layer positioned between the first substrate and the second substrate and including a liquid crystal molecule. At least one of the first alignment layer and the second alignment layer includes a copolymer of cyclobutanedianhydride (CBDA), a diamine, and a compound represented by Chemical Formula 2.In which X of Chemical Formula 2 represents —(CH2)m-O—(CH2)n—, and a sum of m and n is an odd number.