Liquid Crystal Photoalignment Agent Copolymer for Uniform Alignment

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Solution Overview

Problem

Existing liquid crystal display manufacturing methods, such as the rubbing method, often generate minute particles and electrostatic discharge, leading to quality issues in liquid crystal alignment and display uniformity.

Innovation Solution

A liquid crystal photoalignment agent comprising a copolymer of cyclobutane dianhydride and its derivative, which is applied and irradiated to form alignment layers, optimizing afterimages and layer strength by controlling the ratio of reaction units and using ultraviolet exposure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a rubbing method using fiber material is used to align liquid crystals, then liquid crystal alignment is achieved, but minute particles and electrostatic discharge are generated causing quality issues

Engineering Contradiction:
Improveliquid crystal alignment uniformityVSAvoidminute particles and electrostatic discharge
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent replaces the mechanical rubbing method with a photoalignment method using UV irradiation. Instead of physically rubbing the polymer layer with fiber materials to achieve alignment, the invention uses ultraviolet light to induce photopolymerization of the alignment layer, creating aligned molecular structures through light-induced chemical reactions. This substitution eliminates contact between fiber materials and the polymer layer, thereby preventing generation of minute particles and electrostatic discharge while maintaining effective liquid crystal alignment.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the alignment mechanism from mechanical force (rubbing) to optical-chemical parameters (UV irradiation and photopolymerization). By controlling the wavelength and intensity of UV light, the molecular orientation of the alignment layer is controlled, achieving liquid crystal alignment through parameter changes rather than mechanical action. This approach resolves the contradiction by eliminating harmful mechanical contact while preserving alignment functionality.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If a copolymer of cyclobutane dianhydride and its derivative is used as photoalignment agent, then afterimages are optimized and layer strength is improved, but the manufacturing process becomes more complex

Engineering Contradiction:
Improvealignment layer stability and afterimage performanceVSAvoidcopolymer synthesis and manufacturing process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent performs preliminary synthesis of the copolymer alignment layer material before the actual liquid crystal display manufacturing. The copolymer of cyclobutane dianhydride and its derivative is pre-synthesized with controlled composition (5-50 mol% of derivative) to optimize both afterimage performance and layer strength. By preparing the optimized alignment layer material in advance, the complex synthesis process is separated from the main manufacturing line, reducing process complexity during production while ensuring high reliability of the alignment layer.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses a composite copolymer material combining cyclobutane dianhydride and its derivative in specific ratios. This composite structure leverages the complementary properties of both components: the base cyclobutane dianhydride provides structural stability and photoalignment capability, while the derivative component (with substituents like alkyl groups, halogens, or aromatic rings) enhances layer strength and optimizes afterimage characteristics. The composite material approach achieves superior performance while the fixed composition range simplifies manufacturing control.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances the alignment uniformity and strength of liquid crystal layers, reducing afterimages and improving display quality by forming stable alignment layers through photoalignment, thereby addressing the limitations of traditional rubbing methods.

Implementation Method 1

a liquid crystal photoalignment agent comprising a copolymer of cyclobutane dianhydride and its derivative, which is applied and irradiated to form alignment layers

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS10202491B2Liquid crystal photoalignment agent, liquid crystal display device including the same, and method of manufacturing the same
Publication Date: 2019.02.12 SAMSUNG DISPLAY CO LTD
  • US10202491B2 patent drawing
  • US10202491B2 patent drawing
  • US10202491B2 patent drawing

AI summary

A liquid crystal photoalignment agent is provided. The liquid crystal photoalignment agent is a copolymer of a cyclobutane dianhydride (“CBDA”) and a CBDA derivative.