Photocurable Adhesive Laser Curing Carbonization

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Solution Overview

Problem

Conventional photocurable adhesives face challenges in achieving sufficient curing, especially when thick, and are prone to carbonization when directly irradiated with laser light, making them unsuitable for applications replacing soldering or screw fixation.

Innovation Solution

A photocurable adhesive formulation incorporating an epoxy type adhesive component, a light absorption component with a thermal conductivity of at least 0.2 W/m·K before curing and 0.5 W/m·K after curing, and an inorganic filler, with a light absorption component content no more than 0.1 mass%, allowing for effective curing without surface carbonization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Length of stationary object

If the thickness of the photocurable adhesive is increased, then the adhesive can be used for thicker bonds and replace soldering or screw fixation, but the inside of the adhesive becomes insufficiently cured and the surface carbonizes or burns off during laser irradiation

Engineering Contradiction:
Improveadhesive thicknessVSAvoidcuring sufficiency
Core Design Contradiction:
Length of stationary objectVSReliability

Solution Approach 1:

The patent changes the physical parameters of the adhesive by controlling the light absorption component content (0.01-0.1 mass%) and thermal conductivity (0.2-0.5 W/m·K) to enable thick adhesive layers to be cured uniformly by laser irradiation without surface carbonization, resolving the contradiction between adhesive thickness and curing sufficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite adhesive system combining epoxy adhesive component, light absorption component, and inorganic filler to achieve specific thermal and optical properties that enable deep curing while preventing surface damage during laser processing

Inventive Principle:
Principle #40Composite materials

2Productivity

If direct irradiation with laser light is applied to the photocurable adhesive, then curing speed increases and the adhesive can replace soldering or screw fixation, but the surface of the adhesive carbonizes or burns off

Engineering Contradiction:
Improvecuring speedVSAvoidsurface carbonization
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent optimizes the light absorption component content to a narrow range (0.01-0.1 mass%) and controls thermal conductivity (0.2-0.5 W/m·K) to balance laser energy absorption for fast curing while preventing excessive heat concentration that causes surface carbonization

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the light absorption property, which could cause harmful surface carbonization, into a beneficial effect by precisely controlling the absorption component content to enable uniform energy distribution and thorough curing throughout the adhesive layer without surface damage

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The adhesive is sufficiently cured even at increased thicknesses and can be directly irradiated with laser light without significant surface carbonization, enabling its use as a substitute for soldering or screw fixation.

Implementation Method 1

a light absorption component which thermally cures the epoxy type adhesive component by absorption of the laser light

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Implementation Method 2

a thermal conductivity before curing of the photocurable adhesive is no less than 0.2 W/m·K. The thermal conductivity after curing of the photocurable adhesive is no less than 0.5 W/m·K

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS10344191B2Photocurable adhesive
Publication Date: 2019.07.09 DENSO CORP
  • US10344191B2 patent drawing
  • US10344191B2 patent drawing
  • US10344191B2 patent drawing

AI summary

Provided is a photocurable adhesive with which curing by direct irradiation of laser light is possible with almost no occurrence of surface carbonization and which is capable of satisfactory curing even when the coating thickness is increased. A photocurable adhesive, which is cured by irradiation of laser light, is provided. The curable adhesive contains an epoxy adhesive component, a light-absorbing component for thermal curing of the epoxy adhesive component by absorption of laser light, and an inorganic filler. The content of the light-absorbing component is 0.1 mass % or less. The pre-curing thermal conductivity of the photocurable adhesive is at least 0.2 W/m·K and the post-curing thermal conductivity is at least 0.5 W/m·K.