Photocurable Flux Composition for Oxide-Safe Semiconductor Bonding

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Solution Overview

Problem

The challenge lies in developing a flux agent that can facilitate the manufacturing of small and multi-functional semiconductor devices while ensuring effective protection of conductive pads and connecting bumps during the bonding process, while also addressing the removal of metal oxides and impurities.

Innovation Solution

A flux agent comprising a first compound with an ester group and an epoxy group, a fourth compound as a chemical reactant of a second compound with an epoxy group and a third compound with an amine group and a carboxyl group, and a photoinitiator, with specific weight percentages, is used to form protective patterns that cover conductive pads and connecting bumps, facilitating bonding and protecting them from external impurities and metal oxides.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional flux agents are used, then the bonding process can proceed, but the protective patterns cannot effectively prevent metal oxide formation and impurity contamination simultaneously

Engineering Contradiction:
Improveprotection effectivenessVSAvoidmetal oxide and impurity contamination
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The flux agent is applied to the conductive pads and connecting bumps before the bonding process to pre-form protective patterns. This preliminary action creates a protective barrier that prevents metal oxide formation and impurity contamination during subsequent manufacturing steps, ensuring reliable electrical connections without requiring additional protective layers.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The flux agent comprises a composite formulation including a first compound (60-95 wt%), a second compound (5-30 wt%), and a photoinitiator (2-10 wt%). This composite material structure provides both protective functionality and flux properties, enabling simultaneous protection against metal oxides and impurities while facilitating the bonding process.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If the flux agent composition is optimized for protection, then metal oxides are removed effectively, but the manufacturing process complexity increases

Engineering Contradiction:
Improvemetal oxide removalVSAvoidflux agent composition complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The flux agent uses specific weight percentage ranges for each component (first compound: 60-95 wt%, second compound: 5-30 wt%, photoinitiator: 2-10 wt%) to optimize metal oxide removal effectiveness. By controlling these compositional parameters, the formulation achieves effective protection without requiring overly complex manufacturing processes, as the compounds are mixed and applied using standard techniques.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The photoinitiator serves as an intermediary component that enables the formation of protective patterns through photopolymerization. This mediator allows the flux agent to transition from a simple liquid coating to a solid protective pattern upon UV irradiation, providing effective metal oxide removal and protection without adding significant manufacturing complexity.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If protective patterns are formed to cover conductive pads, then electrical connection reliability improves, but the manufacturing process time increases

Engineering Contradiction:
Improveelectrical connection reliabilityVSAvoidmanufacturing process time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The flux agent undergoes a phase transition from liquid to solid through photopolymerization when exposed to UV light. This phase transition allows the formation of solid protective patterns on the conductive pads and connecting bumps in a single rapid step, ensuring electrical connection reliability without requiring multiple processing steps or extended manufacturing time.

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The patent replaces traditional thermal curing processes with photopolymerization initiated by UV light. This substitution eliminates the need for prolonged heating and allows for rapid formation of protective patterns, reducing manufacturing process time while maintaining electrical connection reliability through effective protection of conductive elements.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables efficient formation of protective patterns that maintain the integrity of conductive pads and connecting bumps, allowing for reliable electrical connections and enhanced durability of semiconductor packages.

Implementation Method 1

a photoinitiator, wherein the content of the first compound is 60 wt % to 95 wt % based on 100 wt % of the total agent, the content of the fourth compound is 3 wt % to 33 wt % based on 100 wt % of the total agent, and the content of the photoinitiator is 2 wt % to 10 wt % based on 100 wt % of the total agent

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Implementation Method 2

a fourth compound which is a chemical reactant of a second compound comprising an epoxy group and a third compound comprising an amine group and a carboxyl group

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Data Source

PatentUS20250282908A1Flux agent and semiconductor package including cured product thereof
Publication Date: 2025.09.11 ELECTRONICS & TELECOMM RES INST
  • US20250282908A1 patent drawing
  • US20250282908A1 patent drawing
  • US20250282908A1 patent drawing

AI summary

Provided is a flux agent according to embodiments of the inventive concept, wherein the flux agent includes a first compound including an ester group and an epoxy group, a fourth compound which is a chemical reactant of a second compound including an epoxy group and a third compound including an amine group and a carboxyl group, and a photoinitiator, wherein the content of the first compound is 50 wt % to 60 wt % based on 95 wt % of the total agent, the content of the fourth compound is 3 wt % to 33 wt % based on 100 wt % of the total agent, and the content of the photoinitiator is 2 wt % to 10 wt % based on 100 wt % of the total agent.