Photoemission Electron Microscope for Non-Destructive Oxide Layer Observation

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Solution Overview

Problem

Observing an oxide layer in a resistance variable element without destroying the element, as existing methods require removing or cutting the upper electrode for transmission electron microscope (TEM) observation.

Innovation Solution

An electron microscope system that includes a laser light source, irradiation lens system, energy analyzer, energy slit, and electron beam detector to selectively observe the oxide layer by emitting and dispersing photoelectrons based on energy, allowing non-destructive observation of the oxide layer below the upper electrode.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If transmission electron microscope (TEM) observation is performed on an oxide layer in a resistance variable element, then the oxide layer can be observed, but the upper electrode must be removed or the element must be cut, causing destruction of the sample

Engineering Contradiction:
Improveobservation capabilityVSAvoidsample integrity
Core Design Contradiction:
Measurement precisionVSLoss of substance

Solution Approach 1:

The patent replaces the mechanical destruction method (cutting or removing the upper electrode) with a photoemission electron microscope observation method that uses light to emit electrons from the sample surface. This allows non-destructive observation of the oxide layer by detecting photoelectrons emitted when laser light irradiates the sample, eliminating the need for physical sample preparation that causes damage.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces photoelectrons as an intermediary carrier to transfer information from the oxide layer to the detector. By using photoelectrons emitted from the oxide layer surface as a mediator, the observation can be performed without direct mechanical contact or destruction of the sample structure, enabling non-destructive imaging of the oxide layer and filament.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Difficulty of detecting and measuring

If the upper electrode is removed to observe the oxide layer, then the oxide layer becomes accessible for observation, but the measurement sample is destroyed

Engineering Contradiction:
Improveaccessibility of oxide layerVSAvoidsample preservation
Core Design Contradiction:
Difficulty of detecting and measuringVSReliability

Solution Approach 1:

The patent substitutes mechanical removal of the upper electrode with optical irradiation using laser light. The laser light penetrates or interacts with the upper electrode and oxide layer to generate photoelectrons, allowing observation of the oxide layer through electron emission without physically removing any components, thus preserving sample integrity while maintaining accessibility for observation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the observation parameter from physical access (requiring electrode removal) to optical/electronic detection (using photoemission). By changing the detection method from mechanical to optical-electronic, the oxide layer becomes accessible for observation through photoelectron emission while the sample structure remains intact and preserved.

Inventive Principle:
Principle #35Parameter changes

3Loss of information

If conventional observation methods are used, then the oxide layer can be visualized, but the observation process requires destructive sample preparation

Engineering Contradiction:
Improvestructural informationVSAvoidsample preparation complexity
Core Design Contradiction:
Loss of informationVSEase of manufacture

Solution Approach 1:

The patent replaces complex mechanical sample preparation procedures with a simplified photoemission-based observation method. Instead of requiring electrode removal, cutting, or sectioning, the system uses laser irradiation to directly generate photoelectrons from the intact sample, dramatically simplifying the preparation process while preserving all structural information including the oxide layer and filament formation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the non-destructive observation of specific materials, including filaments in the oxide layer, by selecting the energy of detected electrons, thereby preserving the measurement sample.

Implementation Method 1

a laser light source configured to generate a CW laser; an irradiation lens system configured to irradiate a measurement sample with the CW laser

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Implementation Method 2

a first electron lens system configured to focus the photoelectrons emitted from the measurement sample onto the energy analyzer

Methodology Applied
Scientific EffectElectrostatic lens focusing: Electrostatic Lens

Implementation Method 3

an energy analyzer configured to disperse, depending on energy, photoelectrons emitted from the measurement sample by irradiation with the CW laser

Methodology Applied
Scientific EffectEnergy-dependent dispersion:

Implementation Method 4

a second electron lens system configured to project the photoelectron passed through the energy slit onto the electron beam detector

Methodology Applied
Scientific EffectElectrostatic lens projection: Electrostatic Lens

Data Source

PatentUS11237121B2Electron microscope, and method for observing measurement sample
Publication Date: 2022.02.01 THE UNIV OF TOKYO
  • US11237121B2 patent drawing
  • US11237121B2 patent drawing
  • US11237121B2 patent drawing

AI summary

An electron microscope includes: a laser light source configured to generate a CW laser; an irradiation lens system configured to irradiate a measurement sample with the CW laser; an energy analyzer configured to disperse, depending on energy, photoelectrons emitted from the measurement sample by irradiation with the CW laser; an energy slit configured to allow a photoelectron with a specified energy to pass, among the photoelectrons; an electron beam detector configured to detect the photoelectron passed through the energy slit; a first electron lens system configured to focus the photoelectrons emitted from the measurement sample onto the energy analyzer; and a second electron lens system configured to project the photoelectron passed through the energy slit onto the electron beam detector.