Photoformed Silicone Sensor Membrane Patterning

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Solution Overview

Problem

Existing silicone-based gas permeable membranes for sensors are not directly photoformable, requiring complex indirect methods for patterning, which increases manufacturing costs and reduces yield.

Innovation Solution

A photoformed silicone membrane is created using a directly photoformable organosiloxane polymer that is permeable to gaseous molecules but impermeable to non-gaseous molecules and ions, achieved by applying UV radiation to form a membrane on a surface and then selectively removing unexposed polymer with a developer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If indirect photo-patterning methods are used with non-photoformable silicone materials, then gas permeable membranes can be manufactured, but the manufacturing process becomes complex and costly

Engineering Contradiction:
Improvemembrane performanceVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses a photoresist layer as an intermediary material to enable patterning of non-photoformable silicone copolymer membranes. The photoresist absorbs UV radiation and undergoes chemical changes that allow selective removal, thereby defining the pattern in the underlying membrane without requiring the membrane material itself to be photoactive.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent applies a photoresist coating to the silicone copolymer membrane before attempting to create the pattern. This preliminary step prepares the surface for selective etching by providing a layer that can be differentially removed based on UV exposure, thus enabling subsequent precise patterning of the membrane.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If indirect photo-patterning methods are used with non-photoformable silicone materials, then gas permeable membranes can be manufactured, but manufacturing yield decreases and cost increases

Engineering Contradiction:
Improvemembrane performanceVSAvoidmanufacturing yield
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The photoresist layer serves as a mediator that enables precise patterning with high yield. By using the photoresist to define the pattern areas and then selectively removing only the exposed or unexposed regions (depending on positive or negative resist), the process achieves high precision and consistency, reducing defects and improving overall manufacturing yield.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If indirect photo-patterning methods are used, then patterned membranes can be created, but the process requires multiple steps including coating, exposing, and developing

Engineering Contradiction:
Improvepattern fidelityVSAvoidnumber of process steps
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The photoresist intermediary enables precise pattern transfer through a standardized three-step process: coating the resist, exposing to UV light through a mask, and developing to remove exposed or unexposed regions. This well-established photolithographic approach ensures high pattern fidelity while maintaining reasonable process simplicity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method simplifies the manufacturing process, reduces costs, and improves the reliability and fidelity of microstructure dimensions, allowing for efficient detection of various molecules and ions while maintaining gas permeability and ion impermeability.

Implementation Method 1

applying ultraviolet (UV) radiation to at least a portion of the layer to cause the polymer to form an adhered membrane on the surface

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

a photoformed organosiloxane polymer membrane that is substantially permeable to gaseous molecules and substantially impermeable to non-gaseous molecules and ions

Methodology Applied
Scientific EffectPermeation: Permeation

Data Source

PatentUS8241487B2Photoformed silicone sensor membrane
Publication Date: 2012.08.14 ABBOTT POINT OF CARE INC
  • US8241487B2 patent drawing
  • US8241487B2 patent drawing
  • US8241487B2 patent drawing

AI summary

A sensing device includes a sensing surface, and a matrix overlaying the sensing surface. The sensing device includes a photoformed membrane overlaying at least a portion of the matrix. The photoformed membrane includes a directly photoformed organosiloxane polymer that is substantially permeable to gaseous molecules and substantially impermeable to non-gaseous molecules and ions.