Photolithography Liner Deposition for Fine Pattern Process Margins

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Solution Overview

Problem

The increasing demand for higher device integration and speed in semiconductor manufacturing poses challenges in fabricating integrated circuit devices, particularly due to reduced process margins in exposure processes for patterning fine patterns, which existing technologies struggle to address effectively.

Innovation Solution

A photolithography method incorporating an initiated chemical vapor deposition (iCVD) process, where a liner layer is formed by reacting an initiator and a monomer with multiple carbon bonds, forming a copolymer that is conformally deposited on a substrate and photoresist pattern, allowing for precise etching and patterning without damaging the substrate, and enabling the formation of a trench defining an active pattern.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional photolithography processes are used for patterning fine patterns, then existing process capabilities are maintained, but manufacturing precision and reliability deteriorate due to reduced process margins

Engineering Contradiction:
Improvepatterning precisionVSAvoidprocess reliability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

A liner layer is introduced as an intermediary between the photoresist pattern and the substrate. This liner layer serves as a protective mediator that prevents direct contact and potential damage between the etching process and the substrate, while also providing a controlled interface for precise pattern transfer, thereby improving both manufacturing precision and process reliability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The liner layer is formed in advance before the etching process. This preliminary action prepares a protective and controlled interface that enables subsequent precise patterning operations, ensuring that the substrate is protected and the pattern transfer conditions are optimized before actual etching begins

Inventive Principle:
Principle #10Preliminary action

2Productivity

If higher device integration is pursued to meet demand, then device functionality is improved, but manufacturing difficulty increases due to reduced process margins

Engineering Contradiction:
Improvedevice integrationVSAvoidfabrication complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The liner layer acts as a mediator that simplifies the fabrication process for high integration devices by providing a consistent, controlled interface that enables reliable pattern transfer even at reduced dimensions, thereby supporting higher device integration without proportionally increasing fabrication complexity

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The method enables precise control of the liner layer thickness and composition through the iCVD process, allowing optimization of process parameters to maintain adequate process margins even as device dimensions are reduced for higher integration, thus managing fabrication complexity while improving productivity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method improves the precision and accuracy of the photolithography process, reduces substrate damage, and enhances the reliability of semiconductor device manufacturing by allowing for precise control over pattern formation and etching, thereby addressing the challenges of high integration and speed requirements.

Implementation Method 1

the initiator may include a material that forms a radical by thermal decomposition

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 2

a copolymer may be formed by an initiating reaction between the radical and the monomer

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Implementation Method 3

forming of the liner layer may include a deposition process of reacting an initiator and a monomer with each other

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Data Source

PatentUS20240411227A1Photolithography method and method of manufacturing semiconductor device using the same
Publication Date: 2024.12.12 SAMSUNG ELECTRONICS CO LTD
  • US20240411227A1 patent drawing
  • US20240411227A1 patent drawing
  • US20240411227A1 patent drawing

AI summary

A photolithograph method is provided. The photolithograph method may include forming a photoresist pattern on a substrate and conformally forming a liner layer on the photoresist pattern, wherein the forming of the liner layer includes a deposition process of reacting an initiator and a monomer with each other, the monomer includes multiple bonds between carbon atoms, the initiator includes a material that forms a radical by thermal decomposition, a copolymer is formed by an initiating reaction between the radical and the monomer, and the liner layer includes the copolymer.