Photon-Induced Material Deposition for Microelectronics

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Solution Overview

Problem

Current material deposition techniques, such as 3D printing and photolithography, face limitations including low resolution, high costs, limited material options, and complex multi-step processes, which hinder the efficient patterning and deposition of materials, especially for noble metals and in-situ applications.

Innovation Solution

A photon-induced material deposition method using a mixture of metallate solutions and semiconductor nanoparticles, where a light source focuses on the reagent to induce chemical reduction and optical trapping, allowing for the formation of mechanically rigid deposits with low power consumption and versatility in material selection, including noble metals and insulators.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional photolithography and material deposition methods are used, then material patterning can be achieved, but the process requires multiple separate steps including mask fabrication, material deposition, and photolithography, increasing complexity and cost

Engineering Contradiction:
Improvematerial patterning precisionVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent combines photolithography and material deposition into a single integrated process. A photosensitive material layer containing metal ions is deposited on the substrate, and selective exposure to light simultaneously patterns both the photoresist and triggers in-situ metal deposition through photochemical reduction, eliminating the need for separate mask fabrication and material deposition steps.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The photosensitive material layer serves multiple functions: it acts as the photoresist for patterning, as the source of metal ions for deposition, and as the medium that undergoes photochemical transformation. This multi-functional approach replaces multiple specialized materials and processes with a single versatile system.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Strength

If high power lasers are used for selective laser sintering, then material particles can be sintered to form structures, but the device cost increases and the process requires high power lasers which are expensive

Engineering Contradiction:
Improvestructure formation capabilityVSAvoiddevice cost
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent changes the energy parameter from high power laser sintering to low power light-induced photochemical reactions. Instead of using high power lasers to heat and sinter metal particles, the method uses visible or UV light to induce photochemical reduction of metal ions directly in the photosensitive material layer, achieving structure formation at much lower power levels and reduced device cost.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the thermal-mechanical sintering process with a photochemical process. Instead of using mechanical/thermal energy from high power lasers to fuse particles, the method uses photochemical energy to directly reduce metal ions and form metallic structures through chemical reactions initiated by light exposure.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If direct optical deposition of inorganic nanomaterials is performed, then nanomaterials can be deposited, but the layer thickness is limited to 100 nm due to limited penetration depth

Engineering Contradiction:
Improvedeposition resolutionVSAvoidlayer thickness
Core Design Contradiction:
Manufacturing precisionVSLength of stationary object

Solution Approach 1:

The patent incorporates metal ions within the photosensitive material layer before exposure, distributing them throughout the entire layer thickness. When light exposes the layer, photochemical reduction occurs throughout the volume where metal ions are present, enabling deposition thickness to extend beyond the traditional 100 nm penetration depth limit by having the metal source distributed throughout the layer rather than being deposited from above.

Inventive Principle:
Principle #10Preliminary action

4Manufacturing precision

If conventional material deposition techniques are used, then materials can be deposited, but the resolution is limited to sub-mm levels and the machines are expensive and specialized

Engineering Contradiction:
Improvedeposition resolutionVSAvoiddevice cost and specialization
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The photosensitive material layer contains its own metal ion source, eliminating the need for separate material deposition equipment. The layer self-provides both the photoresist function and the metal source, allowing patterning and metal deposition to occur in a single process using standard photolithography equipment rather than specialized expensive deposition machines.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method achieves high spatial resolution, flexible material deposition, and low-cost, single-step fabrication of conductive and insulating materials, suitable for macroscopic and microscopic scales, with reduced environmental impact and compatibility with optical measurements, enabling in-situ deposition and repair of microelectronics.

Implementation Method 1

focusing a light source on the reagent to form a mechanically rigid deposition in the focus of the light source

Methodology Applied
Scientific EffectPhoto-induced chemical reduction: Photopolymerisation

Implementation Method 2

focusing a light source on the reagent to form a mechanically rigid deposition in the focus of the light source

Methodology Applied
Scientific EffectOptical trapping: Optical Tweezers

Data Source

PatentUS11554541B2Method for a photon induced material deposition and a device therefor
Publication Date: 2023.01.17 THE CHINESE UNIVERSITY OF HONG KONG
  • US11554541B2 patent drawing
  • US11554541B2 patent drawing
  • US11554541B2 patent drawing

AI summary

A method for photon induced material deposition includes providing a first solution, which contains metallate or metal ions, providing a second solution, which contains light sensitive reducing agent, such as semiconductor nanoparticles, mixing the first solution and the second solution to form a reagent on a substrate, and focusing a light source on the reagent to form a mechanically rigid deposition in the focus of the light source.