Photoreactive Compounds for Liquid Crystal Alignment

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Solution Overview

Problem

Current photoalignment materials for liquid crystals lack effective economic manufacturing processes that also provide good optical or electro-optical properties, limiting their application in various devices such as LCDs, decorative, and security applications.

Innovation Solution

A photoreactive compound with a terminal group of formula (I) is developed, featuring a polymerizable group and spacer units, which allows for efficient alignment of liquid crystals through photoalignment processes, enhancing optical and electro-optical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional photoalignment materials are used, then manufacturing processes can be implemented, but the optical and electro-optical properties are insufficient

Engineering Contradiction:
Improveoptical and electro-optical propertiesVSAvoidmanufacturing process efficiency
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent employs composite materials by combining photoreactive groups (such as cinnamyl, coumarin, or benzoxazole groups) with liquid crystal alignment functionalities in a single molecular structure. This composite approach allows the material to simultaneously provide photoalignment capability and excellent optical/electro-optical properties, resolving the contradiction between manufacturing ease and performance quality.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies molecular parameters by introducing specific photoreactive groups with defined chemical structures and photochemical properties. By changing parameters such as the type of photoreactive group, molecular weight, and structural configuration, the material achieves both high-yield photoalignment processes and superior optical/electro-optical characteristics.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If photoalignment materials are designed for good optical properties, then manufacturing costs increase

Engineering Contradiction:
Improveoptical propertiesVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent creates multi-functional photoreactive compounds that serve multiple purposes: they provide photoalignment functionality, ensure good optical properties, and maintain cost-effectiveness. The universal design allows a single compound structure to achieve economic manufacturing through high-yield synthesis while delivering the required optical performance for liquid crystal alignment.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Reliability

If photoalignment materials are designed for good electro-optical properties, then manufacturing complexity increases

Engineering Contradiction:
Improveelectro-optical propertiesVSAvoidmaterial structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent segments the molecular structure into distinct functional units: a photoreactive group (such as cinnamyl, coumarin, or benzoxazole) and a liquid crystal alignment group. This segmentation allows each component to be optimized independently for its specific function while maintaining overall structural simplicity that facilitates economic manufacturing and high-yield production.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound enables high-yield, cost-effective photoalignment processes, improving the optical and electro-optical properties of liquid crystal devices, expanding their applications in displays, security, and decorative fields.

Implementation Method 1

The wording 'polymerizable group' as used in the context of the present invention refers to a functional group that can be subjected to polymerization (optionally with other comonomers) to yield an oligomer, dendrimer or polymer

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentEP2748280B1Photoreactive compounds
Publication Date: 2016.11.30 ROLIC AG
  • EP2748280B1 patent drawing
  • EP2748280B1 patent drawing
  • EP2748280B1 patent drawing

AI summary

The present invention relates to photoreactive compounds that are particularly useful in materials for the alignment of liquid crystals.