Photoreceptor Protective Layer Composition for Solubility and Hardness

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Solution Overview

Problem

Existing compounds with electron transporting structures have insufficient solubility in organic solvents, mechanical strength, and electrical properties, leading to suboptimal performance in protective layers of electrophotographic photoreceptors.

Innovation Solution

A compound with a perylene diimide skeleton and specific side chains, or a combination of compounds with conjugated skeletons, is used to form a protective layer with improved solubility, mechanical strength, and electron transporting properties, enhancing the photoreceptor's electrical and mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If existing compounds with electron transporting structures are used to form a protective layer, then the photoreceptor can be manufactured, but the compound has insufficient solubility in organic solvents

Engineering Contradiction:
Improvesolubility in organic solventsVSAvoidelectrical properties of protective layer
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent modifies the molecular structure of electron transporting compounds by changing parameters such as introducing specific side chains (e.g., alkyl groups with 4-20 carbon atoms) and modifying the core structure (triphenylamine, carbazole, oxadiazole units). These parameter changes improve solubility in organic solvents while maintaining or enhancing electrical properties like electron mobility and charge transport capability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite protective layers by combining electron transporting compounds with hole transporting materials, resins, and other functional materials. This composite approach allows the protective layer to achieve both good solubility (through the resin matrix) and excellent electrical properties (through the synergistic combination of electron and hole transporting materials).

Inventive Principle:
Principle #40Composite materials

2Strength

If existing compounds with electron transporting structures are used to form a protective layer, then the photoreceptor can be manufactured, but the protective layer has insufficient mechanical strength

Engineering Contradiction:
Improvemechanical strength of protective layerVSAvoidelectrical properties of protective layer
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent forms composite protective layers by combining electron transporting compounds with hole transporting materials and resins. The resin component (e.g., polyurethane, epoxy, silicone) provides mechanical strength and structural integrity, while the electron transporting compound maintains electrical properties. This composite structure resolves the contradiction between mechanical strength and electrical performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent assigns different functions to different components within the protective layer: the resin provides mechanical strength and structural support, the electron transporting compound ensures electrical conductivity and charge transport, and the hole transporting material facilitates hole mobility. This local differentiation of quality allows each component to optimize its specific function without compromising overall performance.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound forms a protective layer with high hardness, elastic deformation rate, and excellent solubility, resulting in a photoreceptor with improved residual potential property and surface flatness.

Implementation Method 1

a compound having an electron transporting structure and at least three polymerizable functional groups in one molecule

Methodology Applied
Scientific EffectPolymerization:

Implementation Method 2

X represents a perylene diimide skeleton... the compound has electron transporting property

Methodology Applied
Scientific EffectElectron transport:

Implementation Method 3

The compound of the present invention has excellent solubility in organic solvents

Methodology Applied
Scientific EffectSolubility: Solvation

Data Source

PatentUS20260049081A1Compound, composition, and electrophotographic photoreceptor
Publication Date: 2026.02.19 MITSUBISHI CHEM CORP
  • US20260049081A1 patent drawing
  • US20260049081A1 patent drawing
  • US20260049081A1 patent drawing

AI summary

The present disclosure relates to a compound having one or more polymerizable functional groups.