Electrophotographic Photoreceptor Outermost Layer Density Control

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Solution Overview

Problem

Conventional electrophotographic photoreceptors face challenges in maintaining stable image quality and wear resistance over long-term use, especially under varying environmental conditions, due to contamination and image defects caused by ozone, nitrogen oxides, and mechanical wear, which existing technologies fail to adequately address.

Innovation Solution

The development of an electrophotographic photoreceptor with a photosensitive layer on a conductive substrate, where the outermost layer's film density is optimized by controlling the solvent boiling point and film density gradient, ensuring a slope of 1.50E-4 (g/cm3·°C) or greater and a density difference of 0.030 g/cm3 or less between the surface and substrate, thereby enhancing image stability and wear performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the photoreceptor is used repeatedly under varying environmental conditions, then printing volume increases, but image quality stability and wear resistance deteriorate due to contamination and mechanical wear

Engineering Contradiction:
Improveprinting volumeVSAvoidimage quality stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies parameter changes by optimizing the film density of the outermost layer to be 1.20 g/cm³ or more and controlling the density gradient to be 0.020 g/cm³ or less. These parameter specifications directly address the deterioration issues by creating a denser, more uniform outermost layer that resists contamination and mechanical wear, thereby maintaining image quality stability even after repeated printing operations under varying environmental conditions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by formulating the outermost layer with specific resin components and additives that achieve the target film density and gradient characteristics. The composite structure of the photoreceptor, with its functionally separated layers and optimized outermost layer composition, provides enhanced durability and contamination resistance while maintaining electrical characteristics for stable image quality

Inventive Principle:
Principle #40Composite materials

2Strength

If the outermost layer film density is increased to improve wear resistance, then wear performance improves, but film uniformity and image quality may deteriorate due to excessive density gradient

Engineering Contradiction:
Improvewear resistanceVSAvoidfilm uniformity
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent resolves this contradiction by establishing two simultaneous parameter constraints: film density of 1.20 g/cm³ or more for wear resistance, and density gradient of 0.020 g/cm³ or less for film uniformity. This dual-parameter approach ensures that the outermost layer achieves both high wear resistance and manufacturing precision, preventing image quality deterioration while maintaining enhanced durability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by creating an outermost layer with optimized local density characteristics. The controlled density gradient ensures that while the overall film density is high for wear resistance, the distribution of density throughout the layer remains uniform, preventing localized defects that would compromise image quality

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If conventional photoreceptor structures are used, then manufacturing is simpler, but contamination from ozone and nitrogen oxides causes image defects and reduces durability

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidcontamination resistance
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent employs composite materials by formulating the outermost layer with specific resin components and additives that provide inherent resistance to ozone and nitrogen oxide contamination. This composite structure maintains manufacturing simplicity while significantly improving contamination resistance, as the specialized outermost layer composition prevents harmful substances from penetrating and degrading the photoreceptor

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies parameter changes by specifying the film density of the outermost layer (1.20 g/cm³ or more) and density gradient (0.020 g/cm³ or less) to enhance contamination resistance. These parameter optimizations create a denser, more uniform barrier layer that effectively blocks harmful substances while maintaining ease of manufacture through standardized production processes

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a photoreceptor that maintains stable image quality and excellent wear performance without image defects, even after repeated use and exposure to changing environmental conditions, by controlling the film density and solvent boiling point relationship.

Implementation Method 1

a photosensitive layer having a photoconductive function is disposed on a conductive substrate

Methodology Applied
Scientific EffectPhotoconductivity: Photoconductivity

Data Source

PatentUS10551754B2Method of producing an electrophotographic photoreceptor
Publication Date: 2020.02.04 FUJI ELECTRIC CO LTD
  • US10551754B2 patent drawing
  • US10551754B2 patent drawing
  • US10551754B2 patent drawing

AI summary

A method of producing an electrophotographic photoreceptor composed of a photosensitive layer provided on a conductive substrate, includes, in the formation of an outermost layer, controlling slope k of a straight line obtained by plotting the average film density of outermost layer and boiling point of solvent used for the formation of the outermost layer along the ordinate and the abscissa, respectively, to be 1.50E-4 (g/cm3·° C.) or greater, and adjusting the difference in film density of the outermost layer between the surface side and the side close to the conductive substrate to be 0.030 g/cm3 or less. The electrophotographic photoreceptor has reduced image defects even after long-term use and has excellent wear performance.