Electrophotographic Photoreceptor Surface Layer Composition

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Solution Overview

Problem

Electrophotographic photoreceptors face issues with mechanical durability and image quality due to inadequate surface roughness and composition of the surface layer, leading to defects such as image quality defects and toner slipping or lubricant issues.

Innovation Solution

An electrophotographic photoreceptor with a surface layer containing a cross-linked component derived from guanamine or melamine compounds and a charge-transporting material, along with fatty acid metal salts and fluorine resin particles, where the coverage of these components satisfies specific relationships and surface roughness is maintained between 0.1 μm to 0.3 μm to enhance mechanical durability and image stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the surface layer composition is not optimized, then mechanical durability deteriorates, but increasing cross-linked component content may affect image quality

Engineering Contradiction:
Improvemechanical durabilityVSAvoidimage quality
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent optimizes the surface layer by controlling the content of cross-linked components (0.1-5% by weight) and charge-transporting material (85% or more by weight), along with specific surface roughness (Rz: 0.1-0.3 μm), to simultaneously achieve high mechanical durability and image quality without mutual interference

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The surface layer is constructed as a composite material containing cross-linked components (from guanamine or melamine compounds), charge-transporting materials, and specific additives (fatty acid metal salt and fluorine resin particles), where the synergistic combination of these materials provides both mechanical strength and image formation performance

Inventive Principle:
Principle #40Composite materials

2Strength

If surface roughness is not controlled, then image quality deteriorates, but increasing surface roughness may improve mechanical durability

Engineering Contradiction:
Improvemechanical durabilityVSAvoidimage quality
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent identifies and controls the critical parameter of surface roughness (Rz: 0.1-0.3 μm) as a key factor that simultaneously influences both mechanical durability and image quality, optimizing this parameter to resolve the contradiction between the two requirements

Inventive Principle:
Principle #35Parameter changes

3Strength

If coverage of fatty acid metal salt and fluorine resin particles is not optimized, then mechanical durability deteriorates, but improper coverage may cause image quality defects

Engineering Contradiction:
Improvemechanical durabilityVSAvoidimage quality
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent establishes specific quantitative relationships for the coverage of fatty acid metal salt (Y) and fluorine resin particles (X) that must satisfy Expressions (1) and (2), transforming the qualitative requirement into controllable parameters that simultaneously ensure mechanical durability and prevent image quality defects

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The surface layer incorporates both fatty acid metal salt and fluorine resin particles as functional additives in specific proportions, creating a composite material system where these components work synergistically to provide both mechanical protection and image quality maintenance

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides excellent mechanical durability and stabilized image formation by optimizing the surface layer composition and roughness, preventing defects like image quality issues and toner slipping, while ensuring long-term performance and high image quality.

Implementation Method 1

the surface layer includes a cross-linked component which is a reaction product of compound A and compound B, wherein the compound A is at least one compound selected from guanamine compounds and melamine compounds, and the compound B is a charge-transporting material having at least one substituent selected from —OH, —OCH3, —NH2, —SH, and —COOH

Methodology Applied
Scientific EffectCross-linking reaction: Chemical Bonding

Data Source

PatentUS8822115B2Electrophotographic photoreceptor, process cartridge, image forming apparatus, and image forming method
Publication Date: 2014.09.02 FUJIFILM BUSINESS INNOVATION CORP
  • US8822115B2 patent drawing
  • US8822115B2 patent drawing
  • US8822115B2 patent drawing

AI summary

An electrophotographic photoreceptor includes a conductive substrate, a photosensitive layer, and a surface layer that is provided on the photosensitive layer. The surface layer includes a cross-linked component which is a reaction product of compound A and compound B. The compound A is at least one compound selected from guanamine compounds and melamine compounds, and the compound B is a charge-transporting material. A structure derived from at least one compound selected from the guanamine compounds and the melamine compounds included in the surface layer amounts for 0.1% by weight to 5% by weight, and a structure derived from the charge-transporting material included in the surface layer amounts for 85% by weight or greater. Surface roughness Rz of the surface layer is from 0.1 μm to 0.3 μm, and the surface has at least one compound selected from fatty acid metal salt and fluorine resin particles.