Photorechargeable Battery With Nitrogen Covalent Electron Storage

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Solution Overview

Problem

Existing batteries suffer from low power densities and require toxic or expensive materials, limiting their versatility and scalability, particularly in mobile applications, and there is a lack of efficient electron storage materials that can be reversibly charged by solar energy without applying a potential.

Innovation Solution

Development of an electrochemical device with a nitrogen-containing electron storage material having a two- or three-dimensional covalent structure, capable of intercalating and de-intercalating cations, combined with a hole storage material, to create a photorechargeable or autophotorechargeable battery using earth-abundant elements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional battery materials are used, then batteries can store electrical energy, but they suffer from low power densities and require toxic or expensive materials

Engineering Contradiction:
Improveelectron storage capacityVSAvoidtoxicity and cost of materials
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters by using nitrogen-containing electron storage materials with specific covalent structures (two-dimensional or three-dimensional), replacing conventional toxic materials with earth-abundant elements while maintaining or improving storage capacity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structures combining nitrogen-containing compounds with specific covalent bonding arrangements to achieve both high electron storage capacity and environmental friendliness, creating a new class of battery materials that overcome the limitations of conventional single-material systems

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If conventional batteries are used, then they can provide energy storage, but they have low power densities limiting versatility in mobile applications

Engineering Contradiction:
Improveenergy storage capacityVSAvoidpower density
Core Design Contradiction:
Quantity of substanceVSPower

Solution Approach 1:

The patent modifies the structural parameters of electron storage materials by introducing specific covalent network structures (2D or 3D) that enable faster ion transport and higher power density while maintaining high energy storage capacity through optimized material composition

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If conventional batteries are used, then they can store electrical energy, but they require external voltage for charging and cannot be recharged by solar energy alone

Engineering Contradiction:
Improveenergy storage capacityVSAvoidcharging system complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent merges the energy storage function with photovoltaic energy conversion by integrating nitrogen-containing electron storage materials that can directly utilize solar energy for charging, combining two separate systems (battery + solar panel) into a unified autophotorechargeable battery that eliminates the need for external charging infrastructure

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent enables the battery to recharge itself using solar energy through the intrinsic properties of nitrogen-containing materials that can be directly excited by light to store electrons, allowing the battery to autonomously convert solar energy into stored electrical energy without requiring external power sources or complex charging circuits

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a battery with improved electron storage capacity, increased lifetime, and cycle life, enabling efficient energy harvesting and storage using solar energy without external voltage, and allowing for large-scale production.

Implementation Method 1

a method for harvesting light and storing electrical energy

Methodology Applied
Scientific EffectPhotoelectric Effect: Photoelectric Effect

Implementation Method 2

the nitrogen-containing electron storage material has a two-dimensional or a three-dimensional covalent structure and contains heptazine and/or triazine moieties and is capable of intercalating and de-intercalating cations

Methodology Applied
Scientific EffectIntercalation:

Implementation Method 3

an electrochemical device with a negative electrode comprising a nitrogen-containing electron storage material

Methodology Applied
Scientific EffectElectrochemical Reaction:

Data Source

PatentUS20250364638A1Electrochemical device, batteries, method for harvesting light and storing electrical energy, and detection methods
Publication Date: 2025.11.27 MAX PLANCK GESELLSCHAFT ZUR FOERDERUNG DER WISSENSCHAFTEN EV
  • US20250364638A1 patent drawing
  • US20250364638A1 patent drawing
  • US20250364638A1 patent drawing

AI summary

The present invention relates to an electrochemical device, comprising a negative electrode comprising a nitrogen-containing electron storage material, a positive electrode, and an electrolyte, wherein the nitrogen-containing electron storage material has a two-dimensional or a three-dimensional covalent structure, contains heptazine and/or triazine moieties, and is capable of intercalating and de-intercalating cations. The present invention is further directed to a uses the material, a photorechargeable battery, an autophotorechargeable battery, a redox-flow-battery, a method for harvesting light and storing electrical energy, a method for detecting and removing oxygen, and a method for detecting light.