Photosensitive Layer Carboxylic Acid Anhydride Additive

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Solution Overview

Problem

Electrophotographic photosensitive members face challenges in maintaining stable surface potential and toner image transferring ability, especially in high temperature and humidity environments, due to reduced surface potential and inefficient toner image transfer.

Innovation Solution

Incorporating a carboxylic acid anhydride as an additive in the photosensitive layer with a reduction potential of at least -1.40 V, within specific mass ratios relative to the binder resin, to enhance electric resistance and uniform dispersion, thereby maintaining stable surface potential and improving toner image transferring ability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single-layer photosensitive member is used to implement both charge generating and charge transport functions, then device complexity is reduced, but stable surface potential and toner image transferring ability deteriorate in high temperature and humidity environments

Engineering Contradiction:
Improvestructure complexityVSAvoidsurface potential stability
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent introduces a carboxylic acid anhydride additive with specific reduction potential parameters (≥-1.40V) into the photosensitive layer, changing the chemical composition parameters to improve surface potential stability and toner transfer ability while maintaining the single-layer structure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite photosensitive layer by combining charge generating material, charge transport material, binder resin, and carboxylic acid anhydride additive in specific proportions, achieving enhanced reliability through material composition optimization

Inventive Principle:
Principle #40Composite materials

2Reliability

If the amount of carboxylic acid anhydride additive is increased to improve toner image transferring ability, then manufacturing precision may deteriorate due to dispersion control difficulties

Engineering Contradiction:
Improvetoner image transferring abilityVSAvoiddispersion uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent specifies precise quantitative parameters for the carboxylic acid anhydride additive (0.02-10.00 parts by mass relative to 100 parts by mass of binder resin) to optimize both toner transfer ability and dispersion uniformity, preventing manufacturing defects

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of carboxylic acid anhydride in the photosensitive layer ensures both excellent sensitivity characteristics and toner image transferring ability, preventing image defects caused by reduced toner transfer efficiency.

Implementation Method 1

a electrophotographic photosensitive member includes a photosensitive layer containing a charge generating material, a hole transport material, an electron transport material, and a binder resin

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

The photosensitive layer for example contains a charge generating material, a charge transport material

Methodology Applied
Scientific EffectPhotoconductivity: Photoconductivity

Data Source

PatentEP3355119B1Electrophotographic photosensitive member, process cartridge, and image forming apparatus
Publication Date: 2020.09.30 KYOCERA DOCUMENT SOLUTIONS INC
  • EP3355119B1 patent drawingFigure 1A~1C
  • EP3355119B1 patent drawingFigure 2
  • EP3355119B1 patent drawingFigure 3

AI summary

An electrophotographic photosensitive member (1) includes a conductive substrate (2) and a photosensitive layer (3). The photosensitive layer (3) is a single-layer photosensitive layer. The photosensitive layer (3) contains a charge generating material, a hole transport material, an electron transport material, a binder resin, and an additive. The additive contains a carboxylic acid anhydride. A reduction potential of the carboxylic acid anhydride is at least -1.40 V versus a reference electrode (Ag/Ag+). The carboxylic acid anhydride is contained in an amount of at least 0.02 parts by mass and no greater than 10.00 parts by mass relative to 100 parts by mass of the binder resin.