Electrophotographic Photosensitive Member Surface Layer Particle Configuration

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Solution Overview

Problem

Existing electrophotographic photosensitive members fail to effectively suppress initial image smearing and improve transferability while maintaining improved injection chargeability, as previous technologies either compromise on abrasion resistance or image quality.

Innovation Solution

An electrophotographic photosensitive member with a surface layer containing a binder resin, electroconductive particles, and insulating particles, where specific ratios and dimensions of these particles are optimized to balance chargeability and transferability, including a volume resistivity range for electroconductive particles and exposed heights for both types of particles to prevent excessive conductive paths and enhance point contact with toner.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If electroconductive particles are incorporated into the surface layer to improve injection chargeability, then the injection chargeability is improved, but the surface resistance is remarkably reduced causing initial image smearing

Engineering Contradiction:
Improveinjection chargeabilityVSAvoidinitial image smearing
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies local quality by creating a dual-particle system where electroconductive particles (for charge injection) and insulating particles (for resistance control) are distributed throughout the surface layer. This allows different regions to serve different functions: electroconductive particles provide charge injection pathways while insulating particles maintain sufficient surface resistance to prevent unwanted charge movement and image smearing.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials by combining electroconductive particles and insulating particles within the same surface layer. This composite structure enables the surface layer to simultaneously achieve improved injection chargeability through electroconductive particles while maintaining adequate surface resistance through insulating particles, thereby resolving the contradiction between chargeability and image smearing prevention.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If particles are incorporated to form convex shapes for reducing toner adhesive property, then transferability is improved, but abrasion resistance may be compromised

Engineering Contradiction:
ImprovetransferabilityVSAvoidabrasion resistance
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent applies local quality by having insulating particles create convex shapes on the surface that locally reduce toner adhesion, while the overall surface layer structure maintains abrasion resistance. The convex shapes are formed by the insulating particles protruding from the surface, providing localized functionality without compromising the overall mechanical strength.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses parameter changes by controlling the size, concentration, and distribution of particles in the surface layer to optimize both transferability and abrasion resistance. By adjusting particle diameter, particle-to-binder ratio, and particle distribution, the surface layer achieves appropriate convexity for toner transfer while maintaining sufficient mechanical strength.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the surface resistance is controlled to improve injection chargeability, then charge injection is enhanced, but charge movement on the surface increases causing image smearing

Engineering Contradiction:
Improveinjection chargeabilityVSAvoidimage quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies local quality by creating a dual-particle system where electroconductive particles provide localized charge injection pathways while insulating particles maintain the overall surface resistance. This spatial differentiation allows charge to be injected efficiently at electroconductive particle locations while preventing unwanted charge movement across the surface through the insulating particle network.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials to simultaneously achieve low contact resistance for charge injection and high surface resistance for preventing charge movement. The composite structure of electroconductive and insulating particles working together enables this dual functionality, improving injection chargeability while maintaining image quality.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The optimized particle configuration reduces initial image smearing and enhances transferability by controlling the electroconductive and insulating particles' exposure, ensuring efficient charge injection and toner transfer without compromising abrasion resistance.

Implementation Method 1

electroconductive particles are incorporated into the surface layer of the photosensitive member to control the volume resistivity of the surface of the photosensitive member

Methodology Applied
Scientific EffectElectrical Conductivity: Conduction (electrical)

Implementation Method 2

a volume resistivity of the insulating particles is 10^10 Ω·cm or more

Methodology Applied
Scientific EffectElectrical Resistance: Electrical Resistance

Implementation Method 3

The discharge product absorbs moisture in air to reduce the resistance of the surface of the photosensitive member

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS20240004322A1Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus
Publication Date: 2024.01.04 CANON KK
  • US20240004322A1 patent drawing
  • US20240004322A1 patent drawing
  • US20240004322A1 patent drawing

AI summary

The electrophotographic photosensitive member includes a surface layer containing a binder resin, electroconductive particles, and insulating particles, wherein when a volume resistivity of the insulating particles is represented by R1 [Ω·cm], a volume resistivity of the electroconductive particles is represented by R2 [Ω·cm], a ratio of an area of the insulating particles that are exposed to a total area of the surface layer is represented by S1 [%], a ratio of an area of the electroconductive particles that are exposed to the total area of the surface layer is represented by S2 [%], an average exposed height of the insulating particles exposed to a surface of the electrophotographic photosensitive member is represented by L1 [nm], and an average exposed height of the electroconductive particles exposed to the surface of the electrophotographic photosensitive member is represented by L2 [nm], those parameters satisfy specific relational formulae.