Electrophotographic Photosensitive Member Protection Layer

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Solution Overview

Problem

Electrophotographic photosensitive members experience smeared images and exposure memory issues under high-temperature and high-humidity environments due to inadequate abrasion resistance and moisture infiltration, which affects image quality and durability.

Innovation Solution

A protection layer with a triarylamine structure and cyclic structure, represented by specific general formulas, is applied to the electrophotographic photosensitive member, enhancing frictional force and elasticity while controlling moisture penetration through a defined A-value ratio, thereby suppressing smeared images and maintaining exposure memory.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a protection layer is applied to improve abrasion resistance, then mechanical durability is improved, but smeared images occur due to increased surface resistance and moisture infiltration

Engineering Contradiction:
Improveabrasion resistanceVSAvoidimage quality
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention changes the chemical composition parameters of the protection layer by incorporating specific compounds (compounds 1-6) with defined molecular structures containing nitrogen atoms and aromatic rings. This compositional parameter change enables the protection layer to simultaneously achieve abrasion resistance and maintain electrical properties that prevent smeared images

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite materials by combining the protection layer compound with specific resins (polyester resin, polycarbonate resin, acrylic resin, or polyvinyl butyral resin) in defined weight ratios. This composite structure integrates the wear-resistant properties of the protection layer compound with the mechanical durability and electrical properties of the resin matrix, resolving the contradiction between abrasion resistance and image quality

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If the protection layer composition is optimized for durability, then mechanical strength is improved, but exposure memory increases under high-temperature and high-humidity storage

Engineering Contradiction:
ImprovedurabilityVSAvoidexposure memory
Core Design Contradiction:
Duration of action of stationary objectVSLoss of information

Solution Approach 1:

The invention optimizes the molecular structure parameters of the protection layer compound by incorporating specific functional groups (aromatic rings, nitrogen-containing groups) that provide both durability through strong intermolecular forces and resistance to moisture infiltration, thereby preventing exposure memory while maintaining mechanical strength

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates an inert environment within the protection layer by using compounds with aromatic ring structures and nitrogen-containing groups that are chemically stable and resistant to moisture penetration. This inert chemical environment prevents the electrostatic latent image from deteriorating during high-temperature and high-humidity storage, eliminating exposure memory while preserving durability

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces smeared images and exposure memory issues, ensuring improved image quality and durability even under harsh environmental conditions.

Implementation Method 1

controlling moisture penetration through a defined A-value ratio

Methodology Applied
Scientific EffectMoisture resistance: Hydrophobe

Implementation Method 2

enhancing frictional force and elasticity

Methodology Applied
Scientific EffectFriction: Friction

Data Source

PatentUS10691033B2Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus
Publication Date: 2020.06.23 CANON KK
  • US10691033B2 patent drawing
  • US10691033B2 patent drawing
  • US10691033B2 patent drawing

AI summary

The present invention provides an electrophotographic photosensitive member sequentially including: a support; a photosensitive layer; and a protection layer formed on the support, wherein the protection layer has a triarylamine structure and a specific cyclic structure, and a specific A-value obtained by measurement using total reflection Fourier transform infrared spectroscopy is 0.010 or more and 0.050 or less.