Photosensitive Quantum Dot Composition for Pattern Quality

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current methods for patterning quantum dot-polymer composites in liquid crystal displays face challenges due to poor compatibility between quantum dots and photoresists, leading to agglomeration and inadequate dispersion, which affects the quality and efficiency of pattern formation.

Innovation Solution

A photosensitive composition is developed that includes quantum dots with organic ligands, a carboxylic acid group-containing binder, photopolymerizable monomers, and a combination of photoinitiators, which disperses the quantum dots effectively and controls curing rates to prevent undercut phenomena, allowing for improved pattern quality and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If quantum dots are dispersed in conventional photoresists, then pattern formation can proceed, but poor compatibility leads to agglomeration and inadequate dispersion

Engineering Contradiction:
Improvepattern formation qualityVSAvoidquantum dot dispersion stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent introduces a compatibility modifier as an intermediary substance between quantum dots and photoresist. This modifier contains functional groups that interact with both quantum dots and photoresist components, mediating their interaction to prevent agglomeration while maintaining pattern formation capability. The compatibility modifier acts as a bridge that resolves the incompatibility between the two materials.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the chemical parameters of the photoresist system by incorporating compatibility modifiers with specific functional groups. This changes the chemical environment and interaction parameters, allowing quantum dots to disperse uniformly without agglomering. The parameter change transforms the incompatible system into a compatible one through chemical modification.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If curing rate is increased to improve pattern formation speed, then productivity increases, but undercut phenomena occur reducing pattern quality

Engineering Contradiction:
Improvepattern formation speedVSAvoidpattern quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent applies local quality by using a multi-component photoinitiator system where different photoinitiators operate at different depths and rates. The surface-proximity photoinitiator cures the top layer quickly to prevent undercutting, while the deep-penetration photoinitiator continues curing deeper layers at a controlled rate. This spatial differentiation of curing characteristics allows both speed and quality.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent implements periodic action through sequential or staged exposure methods. The curing process occurs in phases: first a rapid initial cure to establish pattern structure, then a slower completion phase to finish curing without undercutting. This periodic approach to curing rate control enables both high productivity and high pattern quality.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition enables the formation of high-quality quantum dot-polymer composite patterns with enhanced light characteristics and stability, maintaining a blue photo-conversion rate and improving pattern density and developability without the need for organic solvent developing solutions.

Implementation Method 1

a photopolymerizable monomer having a carbon-carbon double bond; and a solvent, wherein the photoinitiator includes a first photoinitiator including an oxime compound and a second photoinitiator including at least one selected from a phosphine oxide compound and an amino ketone compound

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

The plurality of quantum dots may be dispersed by the carboxylic acid group (—COOH)-containing polymer in the composition

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 3

quantum dots (QD) may be used as a light conversion layer in a light emitting diode (LED) or the like by dispersing in a host matrix of an inorganic material or a polymer

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS12055852B2Photosensitive compositions, preparation methods thereof, and quantum dot polymer composite pattern produced therefrom
Publication Date: 2024.08.06 SAMSUNG ELECTRONICS CO LTD
  • US12055852B2 patent drawing
  • US12055852B2 patent drawing
  • US12055852B2 patent drawing

AI summary

A photosensitive composition including: a plurality of quantum dots, wherein the quantum dot includes an organic ligand bound to a surface of the quantum dot; a photoinitiator; a binder including a carboxylic acid group; a photopolymerizable monomer having a carbon-carbon double bond; and a solvent, wherein the photoinitiator includes a first photoinitiator including an oxime compound and a second photoinitiator including at least one selected from a phosphine oxide compound and an amino ketone compound.