Photosensitive Resin Composition for Display Color Filters

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Solution Overview

Problem

Existing color filters in liquid crystal displays face challenges in achieving excellent luminance and heat resistance while maintaining photo-efficiency and color reproducibility, as the patterning process can cause damage to nanophosphors, leading to quenching phenomena and reduced exposure sensitivity.

Innovation Solution

A photosensitive resin composition is developed, incorporating a nanophosphor, an acetophenone-based initiator, and additional initiators like thioxanthone-based, oxime-based, and benzophenone-based initiators, which prevents quenching and enhances exposure sensitivity, ensuring improved patterning reliability and light efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If heat resistance is improved by using nanophosphor in color filter, then luminance characteristic is improved, but photo-efficiency and color reproducibility are decreased due to quenching phenomena during patterning

Engineering Contradiction:
Improveheat resistanceVSAvoidphoto-efficiency
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent applies preliminary action by adding specific photo-polymerization initiators (acetophenone-based, thioxanthone-based, oxime-based, or benzophenone-based) to the photosensitive resin composition before patterning. These initiators are selected to enable effective UV curing at controlled conditions that prevent excessive heat generation and quenching of nanophosphors, thus preserving photo-efficiency while maintaining heat resistance and color reproducibility.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If exposure sensitivity is reduced due to quenching phenomena in patterning process, then color filter manufacturing becomes unreliable, but maintaining high exposure sensitivity causes damage to nanophosphors

Engineering Contradiction:
Improvepatterning reliabilityVSAvoidquenching phenomena
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies parameter changes by carefully controlling the types and concentrations of photo-polymerization initiators in the photosensitive resin composition. By selecting specific initiator combinations (acetophenone-based 1-10 wt%, thioxanthone-based 1-10 wt%, oxime-based 1-10 wt%, or benzophenone-based 1-10 wt% based on total resin composition), the curing parameters are optimized to achieve reliable patterning while minimizing quenching phenomena and protecting nanophosphors from damage.

Inventive Principle:
Principle #35Parameter changes

3Illumination intensity

If pigment is used in color filter, then color filtering function is achieved, but luminance characteristic cannot be secured

Engineering Contradiction:
Improveluminance characteristicVSAvoidcolor filtering function
Core Design Contradiction:
Illumination intensityVSEase of manufacture

Solution Approach 1:

The patent applies composite materials by combining nanophosphors (quantum dots or inorganic phosphors) with photosensitive resin containing specifically selected photo-polymerization initiators. This composite structure replaces traditional pigments while maintaining color filtering function and simultaneously achieving superior luminance characteristics. The nanophosphors convert UV light to visible light wavelengths, enabling both color filtering and high luminance in the same material system.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces quenching phenomena during the manufacturing process, providing a photosensitive resin composition with enhanced exposure sensitivity, improved light efficiency, and reliable patterning, thereby enhancing the performance of color filters in display devices.

Implementation Method 1

a photo-polymerization initiator including an acetophenone-based initiator; and a photo-polymerization compound

Methodology Applied
Scientific EffectPhoto-polymerization: Photopolymerisation

Implementation Method 2

A photosensitive resin composition according to an exemplary embodiment of the present disclosure includes: a nanophosphor

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS10775695B2Photosensitive resin composition and display device using the same
Publication Date: 2020.09.15 SAMSUNG DISPLAY CO LTD
  • US10775695B2 patent drawing
  • US10775695B2 patent drawing
  • US10775695B2 patent drawing

AI summary

A photosensitive resin composition according to an exemplary embodiment of the present invention includes: a nanophosphor; a photo-polymerization initiator including an acetophenone-based initiator; and a photo-polymerization compound, wherein the photo-polymerization initiator further includes at least one among a thioxanthone-based initiator, an oxime-based initiator, and a benzophenone-based initiator.