Photosensitive Resin Composition for OLED Patterning

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Solution Overview

Problem

Current organic light emitting display devices face challenges in achieving optimal reflow characteristics during the patterning process due to high heat resistance requirements, which can lead to defects and inefficiencies in manufacturing.

Innovation Solution

A photosensitive resin composition is developed, comprising a silsesquioxane-based copolymer, a photosensitive compound, and a solvent, with specific chemical formulations and weight ratios, that provides a low heat resistant characteristic while maintaining sufficient photosensitivity and coating properties, allowing for excellent reflow characteristics during the patterning of electrodes and pixel defining layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If high heat resistance materials are used in the patterning process, then thermal stability is improved, but reflow characteristics deteriorate leading to manufacturing defects

Engineering Contradiction:
Improveheat resistanceVSAvoidpatterning quality
Core Design Contradiction:
TemperatureVSManufacturing precision

Solution Approach 1:

The patent modifies the chemical composition parameters of the resin material by incorporating specific silsesquioxane-based copolymers with controlled molecular weights (2,000-10,000) and dispersion degrees (1.5-5.0), which changes the material's thermal response characteristics to achieve both heat resistance and reflow capability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite photosensitive resin composition combining silsesquoxane-based copolymer, photosensitive compound, and solvent in specific weight ratios (20-50 wt% polymer, 20-30 wt% photosensitive compound, 20-60 wt% solvent), where the synergistic interaction between components achieves both thermal stability and reflow characteristics

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If high heat resistance is maintained during patterning, then material stability is improved, but reflow capability deteriorates causing process inefficiency

Engineering Contradiction:
Improvematerial stabilityVSAvoidpatterning efficiency
Core Design Contradiction:
Stability of the object's compositionVSProductivity

Solution Approach 1:

The patent introduces dynamic thermal response characteristics where the resin composition maintains stability at processing temperatures but exhibits reflow behavior at specific temperature ranges (150-200°C glass transition temperature), allowing adaptive response to different process conditions

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent utilizes phase transition properties of the silsesquioxane-based copolymer with glass transition temperature of 150-200°C, where the material transitions from a rigid state during processing to a reflow state during heating, enabling both stability and reflow capability

Inventive Principle:
Principle #36Phase transitions

3Reliability

If excessive heat is applied for patterning, then complete curing is achieved, but electrode edges suffer heat damage

Engineering Contradiction:
Improvecuring completenessVSAvoidheat damage to electrodes
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent replaces thermal curing with photopolymerization using photosensitive compounds that cure upon light exposure, eliminating the need for high-heat processing while achieving complete curing and avoiding thermal damage to electrode edges

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition enables effective reflow and patterning of organic light emitting display devices at lower temperatures, reducing the risk of defects and simplifying the manufacturing process by achieving the desired shape and coverage of electrode edges without excessive heat damage.

Implementation Method 1

provides a low heat resistant characteristic while maintaining sufficient photosensitivity and coating properties, allowing for excellent reflow characteristics during the patterning of electrodes and pixel defining layers

Methodology Applied
Scientific EffectHeat resistance: Heating

Implementation Method 2

maintaining sufficient photosensitivity and coating properties, allowing for excellent reflow characteristics during the patterning

Methodology Applied
Scientific EffectPhotosensitivity: Photopolymerisation

Data Source

PatentUS10494483B2Photosensitive resin composition, organic light emitting display device including the same, and method for manufacturing organic light emitting display device
Publication Date: 2019.12.03 SAMSUNG DISPLAY CO LTD
  • US10494483B2 patent drawing
  • US10494483B2 patent drawing
  • US10494483B2 patent drawing

AI summary

A photosensitive resin composition, an organic light emitting display device, and method for manufacturing an organic light emitting device, the composition including a photosensitive compound; a solvent; and a silsesquioxane-based copolymer, the silsesquioxane-based copolymer being obtained by copolymerizing a compound represented by the following Chemical Formula 1 with at least one of a compound represented by the following Chemical Formula 2, and a compound represented by the following Chemical Formula 3;R1—R2—Si(R3)3  [Chemical Formula 1]R4—Si(R5)3  [Chemical Formula 2]Si(R6)4.  [Chemical Formula 3]