Photosensitive Resin Composition for 350-440 nm Light

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional photosensitive elements exhibit low sensitivity and resolution when exposed to light with a peak wavelength range of 350 nm to 440 nm, making it difficult to form satisfactory resist patterns in printed circuit board and plasma display panel production processes.

Innovation Solution

A photosensitive resin composition containing a binder polymer, a photopolymerizing compound with a polymerizable ethylenic unsaturated bond, a photoradical polymerization initiator, and a compound with a specific formula that enhances optical absorption in the 350 nm to 440 nm wavelength range, allowing for improved sensitivity and resolution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional photosensitive elements are used with light sources having peak wavelength 350 nm to 440 nm, then worker safety is improved (avoiding harmful UV), but sensitivity and resolution deteriorate

Engineering Contradiction:
Improveharmful UV exposureVSAvoidresist pattern resolution
Core Design Contradiction:
Object-affected harmful factorsVSMeasurement precision

Solution Approach 1:

The patent changes the optical absorption parameters of the photosensitive resin composition by incorporating specific compounds (compounds (D1) and (D2) with defined molecular structures) that absorb light in the 350-440 nm range. This allows the use of safer visible light sources while maintaining high sensitivity and resolution for resist pattern formation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite photosensitive resin composition containing multiple components: binder polymer (A), photopolymerizing compound (B), photoradical polymerization initiator (C), and specific light-absorbing compounds (D). This composite structure enables simultaneous achievement of safety (using visible light) and performance (high sensitivity and resolution).

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional photosensitive resin compositions are used, then manufacturing process is simple, but sensitivity and resolution for 350-440 nm light are insufficient

Engineering Contradiction:
Improvephotosensitive element fabricationVSAvoidresist pattern quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent modifies the chemical composition parameters of the photosensitive resin by incorporating specific compounds (D1) and (D2) with defined molecular structures and absorption characteristics. This enables the resin to respond effectively to 350-440 nm light while maintaining standard manufacturing processes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The compounds (D1) and (D2) act as intermediaries that absorb the 350-440 nm light and transfer energy to initiate polymerization of the photopolymerizing compound (B). This intermediary mechanism enables effective resist pattern formation with visible light sources.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The photosensitive resin composition enables the formation of resist patterns with sufficient sensitivity and resolution when exposed to light in the 350 nm to 440 nm range, enhancing the throughput and quality of resist patterns in printed circuit board and plasma display panel production processes.

Implementation Method 1

irradiated with active light rays for photocuring (pattern exposure) of prescribed sections of the photosensitive resin composition

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

a compound with a specific formula that enhances optical absorption in the 350 nm to 440 nm wavelength range

Methodology Applied
Scientific EffectOptical absorption: Absorption (EM radiation)

Data Source

PatentUS8105759B2Photosensitive resin composition, and, photosensitive element, method for forming resist pattern, method for manufacturing printed wiring board and method for manufacturing partition wall for plasma display panel using the composition
Publication Date: 2012.01.31 RESONAC CORP
  • US8105759B2 patent drawing
  • US8105759B2 patent drawing
  • US8105759B2 patent drawing

AI summary

A photosensitive resin composition comprising (A) a binder polymer, (B) a photopolymerizing compound with a polymerizable ethylenic unsaturated bond, (C) a photoradical polymerization initiator containing a 2,4,5-triarylimidazole dimer or its derivative, and (D) a compound represented by the following general formula (1)(wherein R1 and R2 each independently represent C1-20 alkyl, etc., and R3, R4, R5, R6, R7, R8, R9 and R10 each independently represent hydrogen, etc.).