Photosensitive Resin Rapid Curing Light-Shielding Optical Components

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Solution Overview

Problem

Existing photosensitive resin compositions used for light-shielding in optical components, such as those in portable electronic devices, face challenges with slow curing rates and inadequate adhesiveness, requiring additional heat treatment and compromising the size reduction and performance of imaging units.

Innovation Solution

A photosensitive resin composition incorporating a cationically polymerizable compound with an alicyclic epoxy group, a photo-cationic polymerization initiator containing a boron atom, and a light-shielding material, along with a hydroxyl-containing compound, which allows for rapid curing and enhanced adhesiveness, including reflow heat resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a light-shielding material is contained in the curable resin, then light-shielding ability is improved, but ultraviolet irradiation is impeded and curing rate deteriorates

Engineering Contradiction:
Improvelight-shielding abilityVSAvoidcuring rate
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent changes the curing mechanism from UV-based to cationic polymerization initiated by visible light or heat, allowing the resin to cure despite the presence of light-shielding materials. This parameter change in the curing method resolves the contradiction between light-shielding ability and curing rate.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent substitutes the UV irradiation mechanism with a cationic polymerization mechanism that can be initiated by visible light or thermal energy. This replacement allows curing to proceed effectively even when UV light is blocked by light-shielding materials.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If additional heat treatment is applied to achieve curing, then curing completeness is improved, but processing time and energy consumption increase

Engineering Contradiction:
Improvecuring completenessVSAvoidprocessing time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The cationic polymerization process continues effectively under visible light or heat conditions without requiring separate UV irradiation and heat treatment steps. This continuous curing action reduces total processing time while maintaining curing completeness.

Inventive Principle:
Principle #20Continuity of useful action

3Volume of moving object

If the imaging unit is thinned for size reduction, then compactness is improved, but heat resistance and reliability deteriorate

Engineering Contradiction:
Improveimaging unit sizeVSAvoidheat resistance
Core Design Contradiction:
Volume of moving objectVSReliability

Solution Approach 1:

The patent uses a composite resin composition containing cationically polymerizable compounds, photoinitiators, and light-shielding materials that provides both structural integrity and heat resistance in a thinned imaging unit. The composite formulation maintains reliability despite reduced size.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition enables rapid curing and forms a cured product with excellent light-shielding ability and adhesiveness, facilitating the bonding of lenses and forming a light-shielding layer, thereby improving the productivity and thinning of imaging units in electronic appliances.

Implementation Method 1

a photo-cationic polymerization initiator including a cationic moiety and an anionic moiety containing a boron atom

Methodology Applied
Scientific EffectPhoto-cationic polymerization: Photopolymerisation

Data Source

PatentUS9932439B2Photosensitive resin composition and cured article of same, and optical component
Publication Date: 2018.04.03 DAICEL CORP
  • US9932439B2 patent drawing
  • US9932439B2 patent drawing
  • US9932439B2 patent drawing

AI summary

Provided is a photosensitive resin composition that is, after being applied to an adherend surface, rapidly cured by photoirradiation to form a cured product having excellent light-shielding ability and adhesiveness. The present invention relates to a photosensitive resin composition that includes components as follows:(A) a cationically polymerizable compound at least including a compound containing an alicyclic epoxy group and devoid of ester bonds;(B) a photo-cationic polymerization initiator including a cationic moiety and an anionic moiety containing a boron atom; and(C) a light-shielding material.