Phytase Treatment for Ethanol Processing Scale Reduction

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Solution Overview

Problem

Ethanol processing equipment experiences tenacious scale deposits due to phytic acid precipitating with soluble metals, leading to impaired heat transfer and production interruptions, as existing methods fail to effectively address the insoluble organometallic salt formation.

Innovation Solution

The method involves adding a phytase enzyme to ethanol-processing fluids to convert phytic acid salts into soluble inorganic phosphates, thereby reducing deposition and facilitating the removal of insoluble materials from processing equipment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If phytic acid is present in ethanol-processing fluids, then metal solubility is maintained, but insoluble organometallic salt deposits form on processing equipment

Engineering Contradiction:
Improveequipment operation reliabilityVSAvoidinsoluble deposit formation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical form of phosphate compounds from organic phytates to inorganic phosphates through enzymatic hydrolysis using phytase. This parameter change in chemical composition prevents the formation of insoluble organometallic salts while maintaining metal solubility, thereby eliminating deposit formation on processing equipment and improving operational reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces phytase enzyme as an intermediary substance that catalyzes the conversion of phytic acid to inorganic phosphates. This intermediary enzyme mediates the chemical transformation that prevents harmful deposit formation without directly interacting with the metal ions, thereby resolving the contradiction between maintaining metal solubility and preventing insoluble deposit formation

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If scale deposits form on processing equipment, then heat transfer is impeded, but production interruptions occur

Engineering Contradiction:
Improveproduction continuityVSAvoidheat transfer impairment
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent applies preliminary anti-action by adding phytase enzyme to ethanol-processing fluids before scale deposits can form on processing equipment. The enzyme preemptively converts phytic acid to inorganic phosphates, preventing the formation of insoluble organometallic salts that would otherwise impede heat transfer and cause production interruptions, thereby maintaining production continuity

Inventive Principle:
Principle #9Preliminary anti-action

3Quantity of substance

If phytic acid precipitates with soluble metals, then metal solubility is reduced, but deposit removal is required

Engineering Contradiction:
Improvemetal solubilityVSAvoiddeposit removal difficulty
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The patent applies inversion by reversing the conventional approach: instead of trying to remove deposits after they form, it inverts the strategy by preventing deposit formation in the first place through enzymatic conversion of phytic acid to inorganic phosphates. This maintains metal solubility and eliminates the need for difficult deposit removal operations

Inventive Principle:
Principle #13The other way round (Inversion)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively converts insoluble phytate deposits into soluble orthophosphate, preventing scale formation and ensuring uninterrupted ethanol processing by enhancing metal solubility and ease of residue removal from equipment surfaces.

Implementation Method 1

adding an enzyme with phytase activity to the ethanol-processing fluids after fermentation; converting the phytate to orthophosphate by action of the enzyme

Methodology Applied
Scientific EffectEnzyme catalysis: Enzyme

Implementation Method 2

converting phytic acid salts or phytates to inorganic phosphates

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 3

converting the insoluble material to a soluble residue by action of the agent

Methodology Applied
Scientific EffectChemical conversion: Chemical Bonding

Data Source

PatentUS8039244B2Reducing insoluble deposit formation in ethanol production
Publication Date: 2011.10.18 KURITA AMERICA INC
  • US8039244B2 patent drawing

AI summary

The present inventors have surprisingly discovered that phytic acid tenaciously precipitates with soluble metals in food or fuel ethanol-processing fluid, producing insoluble organometallic salt deposit or scale on the processing equipment that must be removed in order to facilitate further ethanol processing. The present invention relates to converting phytic acid salts or phytates to inorganic phosphates to improve metal solubility and reduce deposition within processing equipment.