Piezoelectric Film Patterning via Sacrificial Layer Lift-off

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Solution Overview

Problem

Conventional techniques for patterning piezoelectric films, such as dry etching and lift-off methods, face challenges in achieving high shape accuracy and uniformity of protruding regions, especially for inorganic materials with micron-thick films, leading to taper shapes and increased processing time and cost.

Innovation Solution

A process involving the formation of a selectively removable resist or sacrifice layer in a predetermined pattern, followed by the growth of a pillar-shaped structure film and subsequent lift-off technique to create protruding regions with side faces normal to the base plate, allowing for precise separation and reduced pattern defects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If dry etching processing is used to pattern piezoelectric films, then protruding regions can be formed, but the side faces of the protruding regions develop taper shapes, reducing shape accuracy

Engineering Contradiction:
Improveshape accuracy of protruding regionsVSAvoidtaper shape of side faces
Core Design Contradiction:
Manufacturing precisionVSShape

Solution Approach 1:

A sacrificial layer is deposited beforehand on the base plate before forming the piezoelectric film. This preliminary structure enables subsequent selective removal to create vertically-sided protruding regions, preventing the taper formation that occurs with direct dry etching of the piezoelectric material.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The sacrificial layer acts as an intermediary element that facilitates the formation of accurately shaped protruding regions. By depositing the piezoelectric film over this intermediary layer and then selectively removing portions of both, vertically-sided structures are achieved without directly etching the piezoelectric material at angled angles.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If dry etching processing is used on thick piezoelectric films (1-5 μm), then patterning can be achieved, but the processing time increases significantly

Engineering Contradiction:
Improvepatterning of piezoelectric filmVSAvoidprocessing time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The invention replaces the time-consuming mechanical dry etching process with a deposition-based approach followed by selective removal. Instead of removing material through slow etching, the piezoelectric film is deposited over a sacrificial layer and then patterned by selective removal, which is faster for thick films.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The sacrificial layer is prepared in advance, allowing the piezoelectric film to be deposited uniformly across the entire surface. The subsequent selective removal process is faster than etching through the full thickness of a 1-5 μm piezoelectric film using dry etching methods.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If dry etching processing is used for piezoelectric films, then patterning can be performed, but high vacuum processes are required, increasing costs

Engineering Contradiction:
Improvepatterning capabilityVSAvoidmanufacturing cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The invention substitutes vacuum-based dry etching processes with atmospheric pressure deposition and wet chemical removal processes. The piezoelectric film is deposited using techniques that do not require high vacuum, and the sacrificial layer is removed using chemical etchants that can be applied at atmospheric pressure, thereby reducing manufacturing costs.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The process changes the operating parameters from vacuum conditions to atmospheric pressure conditions. By using deposition methods and chemical removal processes that operate at atmospheric pressure, the expensive vacuum infrastructure and associated costs are eliminated while maintaining patterning capability.

Inventive Principle:
Principle #35Parameter changes

4Length of moving object

If the piezoelectric film thickness is increased to 1-5 μm to achieve desired strain displacement, then larger displacement quantity is obtained, but the film becomes harder to etch with dry etching

Engineering Contradiction:
Improvedisplacement quantityVSAvoidetchability of piezoelectric film
Core Design Contradiction:
Length of moving objectVSEase of manufacture

Solution Approach 1:

The sacrificial layer serves as an intermediary that enables the formation of thick piezoelectric structures (1-5 μm) with vertical sidewalls. By depositing the thick piezoelectric film over the sacrificial layer and then selectively removing portions, the etching difficulty of thick materials is circumvented, as the removal process acts on both the sacrificial layer and overlying piezoelectric film simultaneously.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The sacrificial layer is prepared beforehand to the appropriate thickness and pattern, allowing a thick piezoelectric film (1-5 μm) to be deposited uniformly. The subsequent selective removal process efficiently patterns the thick film without requiring prolonged or complex dry etching, thereby solving the etching difficulty associated with thick piezoelectric materials.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method ensures high shape accuracy and quick patterning of protruding regions regardless of material or thickness, suppressing pattern loss and maintaining smoothness, while avoiding the need for high-vacuum processes, thus reducing costs.

Implementation Method 1

a piezoelectric device provided with a piezoelectric film, which has piezoelectric characteristics such that the piezoelectric film expands and contracts in accordance with an increase and a decrease in electric field applied across the piezoelectric film

Methodology Applied
Scientific EffectPiezoelectric effect: Piezoelectric Effect

Data Source

PatentUS7741755B2Recess-protrusion structure body, process for producing the same, piezoelectric device, and ink jet type recording head
Publication Date: 2010.06.22 FUJIFILM CORP
  • US7741755B2 patent drawing
  • US7741755B2 patent drawing
  • US7741755B2 patent drawing

AI summary

In a step (A), a selectively removable resist layer or a selectively removable sacrifice layer is formed in a predetermined pattern in a protrusion non-forming region on a base plate. In a step (B), a pillar-shaped structure film is formed on a side of the base plate, on which side the resist layer or the sacrifice layer has been formed in the predetermined pattern. The pillar-shaped structure film contains a plurality of pillar-shaped bodies, each of which extends in a direction nonparallel with a base plate surface of the base plate. In a step (C), the resist layer or the sacrifice layer, and a region of the pillar-shaped structure film, which region is located on the resist layer or the sacrifice layer, are removed by use of a lift-off technique. At least one protruding region, which contains the pillar-shaped bodies, is thus formed.