Self-Powered Piezoelectric Catalyst for Light-Shielded Water Treatment

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Solution Overview

Problem

Photocatalysts, activated by light, are ineffective in deep-water or light-shielded environments for decomposing organic matter in water, as they require external light energy for activation.

Innovation Solution

A self-powered piezoelectric structure that combines a catalytic material with a piezoelectric material, allowing activation through externally applied mechanical force to generate piezoelectric potential, enabling catalytic reactions without external light sources, using materials like TiO2, ZnO, or MoS2 with PVDF-TrFE as the piezoelectric polymer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If photocatalyst is used to decompose organic matters in water, then decomposition efficiency is improved, but it cannot be used in deep-water or light-shielded environments

Engineering Contradiction:
Improvedecomposition efficiencyVSAvoidenvironmental adaptability
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The invention changes the activation parameter of the catalyst from light-dependent to piezoelectricity-dependent. By incorporating piezoelectric materials (such as PVDF-TrFE) with the catalytic material, the system can be activated by mechanical stress-induced piezoelectric potential rather than requiring light illumination, enabling operation in deep-water and light-shielded environments.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite catalyst layer combining catalytic materials (such as TiO2, ZnO, or MoS2) with piezoelectric materials. This composite structure allows the catalytic material to be activated by piezoelectric potential generated from mechanical deformation, eliminating the need for light sources while maintaining catalytic functionality.

Inventive Principle:
Principle #40Composite materials

2Reliability

If light illumination lamp is provided to activate photocatalyst, then catalytic reaction is activated, but external energy source is required

Engineering Contradiction:
Improvecatalyst activationVSAvoidexternal energy requirement
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The invention makes the catalyst system self-activating through piezoelectric effect. The catalytic material embedded in or combined with piezoelectric material can be activated by piezoelectric potential generated from mechanical deformation of the substrate, eliminating the need for external light sources or energy input.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The invention replaces the optical activation mechanism (light illumination) with a mechanical activation mechanism (piezoelectric potential generation through mechanical stress). This substitution allows catalyst activation without requiring light energy input.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If catalytic material is mixed with piezoelectric material, then self-activation is achieved, but catalytic material exposure is reduced

Engineering Contradiction:
Improveself-activation capabilityVSAvoidcatalytic material exposure area
Core Design Contradiction:
ReliabilityVSArea of stationary object

Solution Approach 1:

The invention applies local quality by creating regions with different catalytic material concentrations or exposure levels within the catalyst layer. This allows optimization of both piezoelectric activation (requiring intimate contact between materials) and catalytic reaction (requiring material exposure to reactants).

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention utilizes porous structures in the catalyst layer to increase the effective surface area of catalytic material while maintaining close contact with piezoelectric material. The porous architecture allows reactants to access catalytic sites while the piezoelectric effect can still be effectively transmitted through the structure.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables effective decomposition of organic matter in water even in deep-water or light-shielded environments, enhancing catalytic reaction efficiency by exposing catalytic materials to mechanical deformation, thus eliminating the need for external light sources.

Implementation Method 1

when a force is externally applied to the base material, the catalytic material in the catalyst layer is activated by a potential generated from the piezoelectric material in the catalyst layer

Methodology Applied
Scientific EffectPiezoelectric effect: Piezoelectric Effect

Implementation Method 2

The photocatalyst generates therein electrons and holes by using the light and decomposes water into hydroxide (—OH) and proton (H+) by using the same. By the oxidation/reduction process of the water, it is possible to decompose the organic matters in the water

Methodology Applied
Scientific EffectPhotocatalysis: Photo-oxidation

Implementation Method 3

a catalyst layer formed by using a mixture of a catalytic material, which can be activated when the energy is applied thereto from an outside

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS9925523B2Self-powered piezoelectric structure and method of manufacturing the same
Publication Date: 2018.03.27 IND ACADEMIC COOP FOUND YONSEI UNIV
  • US9925523B2 patent drawing
  • US9925523B2 patent drawing
  • US9925523B2 patent drawing

AI summary

According to an illustrative embodiment of the present invention, a self-powered piezoelectric structure is provided which includes a base material that can be bent by an externally applied force, and a catalyst layer formed on the base material, wherein the catalyst layer is formed by using a mixture of a catalytic material, which can be activated when the energy is applied thereto from an outside, and a piezoelectric material.