Piezoelectric Device Moisture Shielding Layer

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Solution Overview

Problem

Ink jet recording heads with piezoelectric actuators face issues due to moisture invasion, leading to delamination and cracks between layers, especially in high temperature and high humidity environments, as zirconium oxide becomes brittle and prone to damage.

Innovation Solution

A piezoelectric device with a substrate, diaphragm, and piezoelectric actuator laminated in a specific order, featuring layers of silicon, metal elements like chromium and titanium, and silicon nitride, with a zirconium layer between the diaphragm and the actuator, and a moisture shielding layer on the actuator side to prevent moisture invasion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a diaphragm with an elastic film and insulator film is used in a piezoelectric actuator, then the basic functionality is achieved, but moisture invades the diaphragm in high temperature and high humidity environments, causing the zirconium oxide layer to become brittle and leading to delamination and cracks

Engineering Contradiction:
Improvedurability of piezoelectric actuatorVSAvoidmoisture invasion
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The diaphragm is divided into multiple functional layers: an elastic film layer (first layer) providing mechanical flexibility, and an insulator film layer (second layer) providing moisture barrier and electrical insulation. This segmentation allows each layer to specialize in its function, with the insulator film specifically protecting against moisture invasion that causes brittleness in zirconium oxide.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite structure combining an elastic film (e.g., silicon oxide) and an insulator film (e.g., zirconium oxide, silicon nitride) to create a diaphragm that simultaneously provides mechanical elasticity and moisture resistance. This composite material approach resolves the contradiction by integrating materials with complementary properties.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the insulator film is formed by thermal oxidation of zirconium, then good electrical insulation is achieved, but the zirconium oxide becomes brittle when moisture invades, causing delamination and cracks

Engineering Contradiction:
Improveelectrical insulation performanceVSAvoidresistance to delamination and cracks
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The elastic film acts as an intermediary layer between the insulator film and the piezoelectric actuator. This intermediate layer absorbs stress and prevents direct transmission of mechanical stresses that would otherwise cause delamination and cracks in the brittle zirconium oxide insulator film, while maintaining electrical insulation performance.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the physical and chemical parameters of the diaphragm structure by selecting specific materials with appropriate properties: the elastic film provides mechanical compliance while the insulator film provides electrical insulation and moisture resistance. By optimizing material composition and layer thickness, the system achieves both electrical insulation and resistance to delamination.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively suppresses moisture invasion, prevents embrittlement of the zirconium oxide layer, and reduces the risk of delamination and cracks, enhancing the durability and reliability of the ink jet recording head.

Implementation Method 1

a piezoelectric actuator provided on the diaphragm, and causes a pressure change in the ink in the pressure chamber by driving the piezoelectric actuator

Methodology Applied
Scientific EffectPiezoelectric effect: Piezoelectric Effect

Implementation Method 2

The elastic film is formed by thermally oxidizing one surface of the silicon single crystal substrate

Methodology Applied
Scientific EffectThermal oxidation: Oxidation

Implementation Method 3

The insulator film is formed by thermally oxidizing a layer of zirconium alone formed on the elastic film by a sputtering method or the like

Methodology Applied
Scientific EffectThermal oxidation: Oxidation

Data Source

PatentUS11938731B2Piezoelectric device and liquid ejecting head
Publication Date: 2024.03.26 SEIKO EPSON CORP
  • US11938731B2 patent drawing
  • US11938731B2 patent drawing
  • US11938731B2 patent drawing

AI summary

A substrate, a diaphragm, and a piezoelectric actuator are laminated in this order in a first direction, the diaphragm includes a first layer containing silicon as a constituent element, a second layer disposed between the first layer and the piezoelectric actuator, and containing any one or both of at least one metal element selected from the group made of chromium, titanium, aluminum, tantalum, hafnium, and iridium, and silicon nitride, as a constituent element, and a third layer disposed between the second layer and the piezoelectric actuator and containing zirconium as a constituent element, and a fourth layer containing any one or both of at least one metal element selected from the group made of chromium, titanium, aluminum, tantalum, hafnium, and iridium, and silicon nitride, as a constituent element is provided on the third layer on a piezoelectric actuator side.