Piezoelectric Probe Vibration for Bias-Free Surface Charge Measurement

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Solution Overview

Problem

Existing methods for measuring microscopic electrical properties of material surfaces, such as those using Kelvin probe force microscope (KPFM), electrostatic force microscope (EFM), and conductive atomic force microscope (CAFM), suffer from inaccuracies due to the application of AC and DC voltages affecting the sample material, leading to unreliable determination of charge density and work function.

Innovation Solution

A method and apparatus utilizing a piezoelectric ceramic to induce vibration of a probe above the sample material, measuring the target contact potential difference and induced alternating current amplitude to determine the work function and charge density without applying AC or DC voltages, using a pre-stored amplitude determination function based on resonant frequency and capacitance changes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If AC bias voltage and DC voltage are applied between the probe and sample material to measure electrical properties, then charge density and work function can be determined, but the applied voltages affect the electrical properties of the sample material, resulting in inaccurate measurement results

Engineering Contradiction:
Improvemeasurement accuracy of electrical propertiesVSAvoideffect of applied voltages on sample material
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and removes the harmful AC and DC bias voltages from the measurement system. Instead of applying voltages between the probe and sample, the invention uses only AC voltage applied to the piezoelectric ceramic to drive probe vibration, eliminating the voltage application that was causing measurement inaccuracies while preserving the ability to measure electrical properties through contact potential difference and induced current.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces the electrical field-based measurement approach (applying voltages to induce current) with a mechanical vibration-based approach. The probe is driven to vibrate mechanically via piezoelectric ceramic, and electrical properties are measured through the mechanical vibration-induced effects, specifically through contact potential difference and induced alternating current during vibration, rather than through direct voltage application.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Measurement precision

If EFM uses piezoelectric ceramic to drive probe vibration and measures amplitude and phase changes, then qualitative determination of charge density can be made, but there is no exact correspondence between vibration parameters and electrostatic force magnitude, preventing accurate quantitative measurement

Engineering Contradiction:
Improvequantitative measurement accuracyVSAvoidloss of quantitative information
Core Design Contradiction:
Measurement precisionVSLoss of information

Solution Approach 1:

The patent introduces feedback mechanisms to establish exact correspondence between vibration parameters and electrostatic force. By measuring both the contact potential difference and the induced alternating current amplitude during probe vibration, and using these measurements in calculation formulas, the system achieves quantitative determination of charge density and work function, converting the qualitative EFM approach into a quantitative measurement system.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent changes the measurement parameters from simple amplitude and phase detection to include contact potential difference measurement and induced alternating current amplitude measurement. These parameter changes enable quantitative calculation of electrical properties through established physical relationships, transforming the measurement system from qualitative to quantitative capability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Accurately determines the work function and charge density of the sample material's surface by measuring the induced alternating current amplitude and contact potential difference, improving measurement precision without the interference of external voltages.

Implementation Method 1

applying an alternating voltage on a piezoelectric ceramic so that a probe fixed on the piezoelectric ceramic vibrates

Methodology Applied
Scientific EffectPiezoelectric effect: Piezoelectric Effect

Implementation Method 2

measuring a target contact potential difference between the probe and the sample material, and determining a target amplitude of an induced alternating current generated due to the vibration of the probe

Methodology Applied
Scientific EffectElectromagnetic induction: Electromagnetic Induction

Data Source

PatentUS12416657B2Method and apparatus for measuring electrical properties of sample material, device and medium
Publication Date: 2025.09.16 BEIJING INST OF NANOENERGY & NANOSYST
  • US12416657B2 patent drawing
  • US12416657B2 patent drawing
  • US12416657B2 patent drawing

AI summary

A method and an apparatus for measuring an electrical property of a sample material are provided. In the method, an alternating voltage is applied to a piezoelectric ceramic so that a probe fixed on the piezoelectric ceramic vibrates above a surface of the sample material, a target contact potential difference between the probe and the sample material is measured, and a target amplitude of an induced alternating current generated due to the vibration of the probe above the surface of the sample material, a target work function of the surface of the sample material is determined according to the target contact potential difference and a determined work function of the probe, and a target charge density of the surface of the sample material is determined according to the target amplitude, the target contact potential difference, and a pre-stored target amplitude determination function for the induced alternating current.