Wafer-Bonded Piezoelectric Chemical Sensor Fabrication

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Solution Overview

Problem

Existing chemical sensor fabrication methods face challenges in forming reliable sensing layers that maintain functionality under varying temperatures and mechanical stresses, particularly when integrating piezoelectric materials and nano-composite structures.

Innovation Solution

A method involving the formation of a sensor structure between two wafers, where a piezoelectric material is used in one wafer and a sensing layer is deposited through a hole in the other, using techniques like direct printing and thermo-compression bonding with spacer materials that match thermal expansion coefficients, to create a stable and sensitive chemical detection system.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If sensing layers are formed using conventional fabrication methods, then the sensor structure can be created, but the sensing layers suffer from mechanical and thermal stress that reduces their sensitivity and functionality

Engineering Contradiction:
Improvesensing layer functionalityVSAvoidmechanical and thermal stress
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The fabrication process is divided into separate stages: first forming the piezoelectric substrate and sensor structures, then adding the sensing layer in a subsequent step. This segmentation allows each component to be optimized independently and reduces cumulative stress on the sensing layer.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The piezoelectric substrate and sensor structures are fully formed and stabilized before the sensing layer is deposited. This preliminary action ensures that the substrate is ready to provide mechanical support and stress compensation before the sensitive sensing layer is introduced.

Inventive Principle:
Principle #10Preliminary action

2Manufacturing precision

If the sensing layer is deposited after wafer bonding, then the sensor structure is already formed, but accessing the sensing layer requires removing or modifying the wafer structure

Engineering Contradiction:
Improvesensing layer deposition accuracyVSAvoidwafer structure modification
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

A hole is drilled through the first wafer to provide direct access to the sensing layer location. This extraction approach allows the sensing layer to be deposited and accessed without requiring complex modifications to the bonded wafer structure.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The hole in the first wafer acts as an intermediary access path, allowing deposition materials to reach the sensing layer through a simple aperture rather than requiring the sensing layer to be exposed by complex structural modifications.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If spacer materials with mismatched thermal expansion coefficients are used, then the wafer bonding process is simpler, but the sensor experiences thermal stress that damages the sensing layer

Engineering Contradiction:
Improvewafer bonding processVSAvoidthermal stress
Core Design Contradiction:
Ease of manufactureVSTemperature

Solution Approach 1:

The thermal expansion coefficient is changed to match between the spacer material and the wafer materials. This parameter matching eliminates differential thermal expansion and the associated stresses that would damage the sensing layer during temperature variations.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The spacer material is specifically selected or engineered to have a thermal expansion coefficient that matches the average of the two wafer materials. This thermal expansion matching prevents stress buildup during thermal cycling and maintains sensing layer integrity.

Inventive Principle:
Principle #37Thermal expansion

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the creation of chemical sensors that effectively detect and measure chemical presence/concentration with reduced mechanical and thermal stress, preserving the sensitivity and functionality of the sensing layers, even at high temperatures.

Implementation Method 1

The second wafer includes a piezoelectric material

Methodology Applied
Scientific EffectPiezoelectric effect: Piezoelectric Effect

Implementation Method 2

The spacer material could include frit glass paste that is cured into frit glass, where the frit glass has a thermal coefficient of expansion at least approximately equal to average thermal coefficients of expansion for the first and second wafers

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 3

forming the hole through the first wafer includes using ultrasonic milling

Methodology Applied
Scientific EffectUltrasonic vibration: Ultrasonic Vibration

Data Source

PatentUS8372674B2Method for chemical sensor fabrication and related sensor
Publication Date: 2013.02.12 HONEYWELL INTERNATIONAL INC
  • US8372674B2 patent drawing
  • US8372674B2 patent drawing
  • US8372674B2 patent drawing

AI summary

A method includes forming a hole in a first wafer and forming a sensor structure in or on a second wafer. The second wafer includes a piezoelectric material. The method also includes bonding the first wafer and the second wafer, where the sensor structure is located between the wafers. The method further includes forming a sensing layer by depositing material between the wafers through the hole in the first wafer. The sensing layer could be formed by depositing a sensing layer material on the second wafer using direct printing. Also, the hole through the first wafer could be formed using ultrasonic milling, micro-drilling, laser drilling, wet etching, and/or plasma etching. A spacer material could be used to bond the wafers together, such as frit glass paste or an organic adhesive. Trenches could be formed in the first wafer to facilitate easier separation of multiple sensors.