Pigment Layer for High-Contrast Glass Marking

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Solution Overview

Problem

Current methods for labeling substrates, particularly glass, face challenges in achieving quick, precise, and secure labeling that is resistant to forgery, damage, and environmental influences, while maintaining high contrast and resolution.

Innovation Solution

A pigment layer based on a polymer matrix containing a titanium donor and carbon donor, which reacts with high-energy radiation to form titanium carbide, providing a high-contrast, durable marking without the need for glass frit or materials that melt under energy exposure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional sandblasting technology is used to mark glass surfaces, then labeling can be achieved, but the marking has low contrast and requires mechanical removal of glass material which reduces mechanical stability

Engineering Contradiction:
Improvemarking contrastVSAvoidmechanical stability
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent introduces a pigment layer as an intermediary substance between the laser and the glass substrate. This pigment layer absorbs laser energy and converts it to heat, which then marks the glass without requiring mechanical removal of glass material. The pigment layer acts as a mediator that enables high-contrast marking while preserving the mechanical integrity of the glass.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces the mechanical sandblasting process with a thermal process using laser irradiation on a pigment layer. Instead of mechanically removing glass material through sandblasting, the system uses laser-induced heating of the pigment layer to create a permanent mark on the glass, thereby substituting mechanical action with thermal energy conversion.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If laser material evaporation (LTF process or PLD) is used, then a chemical-physical bond is created on the substrate, but the process complexity increases and requires vaporized material deposition

Engineering Contradiction:
Improvebond strengthVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent extracts and separates the pigment layer from the final marking process. Instead of using complex laser transfer film systems with carrier layers and adhesive layers that require vaporization and deposition, the invention uses a simple pigment layer that is directly applied to the substrate and activated by laser irradiation, removing unnecessary components and simplifying the overall process.

Inventive Principle:
Principle #2Taking out (Extraction)

3Ease of manufacture

If direct printing or painting is used for labeling, then material application is simple, but the label can be easily washed or scratched off reducing reliability

Engineering Contradiction:
Improvematerial application simplicityVSAvoidlabel durability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent utilizes phase transition of the pigment layer material under laser irradiation. The laser energy causes the pigment layer to undergo thermal decomposition and chemically bond with the glass substrate, transforming from a simple applied coating to a permanently bonded marking. This phase transition ensures the marking cannot be easily removed while maintaining simple application procedures.

Inventive Principle:
Principle #36Phase transitions

4Productivity

If high laser power is used for burning in markings, then high spatial resolution and quick labeling are achieved, but decomposition products may have corrosive effects and mechanical stability may be influenced

Engineering Contradiction:
Improvelabeling speedVSAvoidcorrosive decomposition products
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent carefully controls the laser irradiation parameters including power, pulse duration, and scanning speed to optimize the marking process. By adjusting these parameters, the system achieves high labeling speed and spatial resolution while maintaining the glass substrate's mechanical stability and minimizing the formation of corrosive decomposition products through controlled thermal processing.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables permanent, high-contrast, and high-resolution markings on glass substrates with excellent temperature resistance and mechanical stability, resistant to environmental factors and forgery, using a process that does not damage the substrate.

Implementation Method 1

the polymer matrix reacts with pulverization when irradiated with high-energy radiation. During pulverization, free carbon is formed and the titanium compound is broken down

Methodology Applied
Scientific EffectPulverization: Laser Ablation

Implementation Method 2

As a marking, a new titanium compound, in particular titanium carbide, is deposited on the substrate to be marked

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Data Source

PatentEP2078614B1Pigment layer and method for long-term inscription of a substrate with high-energy radiation
Publication Date: 2014.06.04 TESA SE
  • EP2078614B1 patent drawingFigure 1
  • EP2078614B1 patent drawingFigure 2
  • EP2078614B1 patent drawingFigure 3

AI summary

Pigment layer, particularly for the permanent marking of glass (1), based on a polymer matrix (3) which reacts predominantly with pulverization to a high-energy beam (2), particularly laser irradiation, containing at least one titanium donor (31) and a carbon donor (32) which provides free carbon upon energy irradiation. A reaction takes place between the titanium donor and the carbon donor upon energy irradiation. Titanium carbide (34) is deposited on the surface of the glass.