Pipe Threaded Joint Coating for Thermal Adhesion and Galling Resistance

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Solution Overview

Problem

Existing solid lubricant coatings for threaded joints in oil country tubular goods face adhesion property degradation at high and low temperatures, leading to decreased galling resistance and corrosion resistance, due to differences in thermal expansion coefficients with the base metals.

Innovation Solution

A composition for forming a solid lubricant coating comprising a binder, a lubricant additive, an anti-rust additive, and a plasticizer, which provides high adhesion properties across a wide temperature range by including bis(2-ethylhexyl) adipate or bis(2-ethylhexyl) sebacate as a plasticizer, along with ethylene vinyl acetate resin, polyolefin resin, earthy graphite, and calcium ion-exchanged silica, applied to the contact surfaces of threaded joints.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a solid lubricant coating is applied to improve galling resistance, then galling resistance is improved, but adhesion properties deteriorate at high and low temperatures due to thermal expansion differences

Engineering Contradiction:
Improvegalling resistanceVSAvoidadhesion property stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent modifies the chemical composition parameters of the coating by incorporating specific plasticizers (bis(2-ethylhexyl) adipate or bis(2-ethylhexyl) sebacate) at controlled concentrations (0.1-5 mass%). This compositional parameter change allows the coating to maintain adhesion stability across extreme temperature ranges while preserving galling resistance properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite coating material combining multiple components: binder (ethylene vinyl acetate resin or polyolefin resin), lubricant additive (earthy graphite), anti-rust additive (calcium ion-exchanged silica), and plasticizer. This composite structure synergistically addresses both galling resistance and thermal adhesion stability that cannot be achieved with single materials.

Inventive Principle:
Principle #40Composite materials

2Reliability

If heavy metal-containing compound greases are used to improve galling resistance, then galling resistance is improved, but environmental harm increases due to heavy metal content

Engineering Contradiction:
Improvegalling resistanceVSAvoidenvironmental impact
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and eliminates heavy metal components (Pb, Zn, Cu) from the traditional compound grease formulation. By removing these harmful substances while retaining the essential lubrication function through alternative materials like earthy graphite and specialized plasticizers, the solution achieves galling resistance without environmental contamination.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces expensive and environmentally harmful heavy metal-based compound greases with a cost-effective, environmentally benign coating system using organic plasticizers and inorganic additives. This substitution provides comparable or superior performance while eliminating long-term environmental liabilities associated with heavy metal disposal.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Stability of the object's composition

If the coating maintains sufficient adhesion at extreme temperatures, then adhesion stability is improved, but the coating may become too soft at high temperatures losing lubricity

Engineering Contradiction:
Improveadhesion stabilityVSAvoidcoating hardness
Core Design Contradiction:
Stability of the object's compositionVSStrength

Solution Approach 1:

The patent carefully controls the plasticizer concentration parameter (0.1-5 mass%) to achieve optimal balance. This precise parameter control ensures the coating remains sufficiently soft for adhesion and lubricity while avoiding excessive softening that would compromise structural integrity and load-bearing capacity at elevated temperatures.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates different functional zones within the coating structure where the binder provides structural hardness and load-bearing capacity, while the plasticizer concentrates in specific regions to maintain adhesion and flexibility. This spatial differentiation of properties allows simultaneous achievement of hardness and adhesion stability.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solid lubricant coating exhibits excellent galling resistance and corrosion resistance even when exposed to high and extremely low temperatures, maintaining adhesion properties and preventing delamination, thus enhancing the performance of threaded joints under varying environmental conditions.

Implementation Method 1

it has become increasingly important that solid lubricant coatings have high adhesion properties even when repeatedly exposed to high temperatures and extremely low temperatures

Methodology Applied
Scientific EffectGlass transition:

Implementation Method 2

a binder, a lubricant additive, an anti-rust additive, and a plasticizer

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 3

The threaded portions and unthreaded metal contact portions of the pin and the box repeatedly experience strong frictional sliding during thread fastening and unfastening of the pipes

Methodology Applied
Scientific EffectLubrication: Lubrication

Data Source

PatentUS11396961B2Composition, threaded joint for pipes including solid lubricant coating formed from the composition, and method for producing the threaded joint for pipes
Publication Date: 2022.07.26 VALLOUREC MANNESMANN OIL & GAS FRANCE
  • US11396961B2 patent drawing
  • US11396961B2 patent drawing

AI summary

A threaded joint for pipes disclosed herein includes a pin and a box. The pin and the box each include a contact surface including a threaded portion and a metal contact portion. The threaded joint for pipes includes a solid lubricant coating on at least one of the contact surfaces of the pin and the box, the solid lubricant coating including a binder, a lubricant additive, an anti-rust additive, and a plasticizer.