Piston Ring Coating with Graded Nitrogen DLC for Friction and Wear

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Solution Overview

Problem

Existing sliding elements, such as piston rings, face challenges in achieving a balance between low friction and wear resistance due to changes in layer properties with DLC coatings of specific thicknesses, and PVD coatings based on hard materials like chromium nitride do not adequately meet the required low coefficients of friction.

Innovation Solution

A sliding element with a coating structure from the inside outwards comprising an adhesive layer, a metal-containing DLC layer with amorphous carbon and tungsten, and a nitrogen-doped metal-free DLC layer, where the nitrogen doping reduces residual stresses and allows for thicker, more stable top layers, optimized through PVD and PA-CVD processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If DLC coating layer thickness is increased to reduce friction, then friction coefficient is reduced, but layer properties change and service life is compromised

Engineering Contradiction:
Improvefriction coefficientVSAvoidservice life
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The coating is divided into three distinct layers: an adhesive layer (5-20 nm thick) for substrate bonding, a metal-containing DLC layer (5-20 μm thick) for low friction, and a metal-free DLC layer (0.5-5 μm thick) for wear resistance. This segmentation allows each layer to optimize its specific function without compromising the others, resolving the contradiction between friction reduction and service life.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The coating uses composite material structure combining different DLC variants with distinct properties. The metal-containing DLC layer provides low friction coefficient while the metal-free DLC layer provides high wear resistance, and the adhesive layer ensures strong substrate bonding. This composite approach allows the system to achieve both low friction and long service life simultaneously.

Inventive Principle:
Principle #40Composite materials

2Reliability

If DLC coating layer thickness is decreased to maintain layer properties, then service life is improved, but friction coefficient increases

Engineering Contradiction:
Improveservice lifeVSAvoidfriction coefficient
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The coating is divided into three distinct layers: an adhesive layer (5-20 nm thick) for substrate bonding, a metal-containing DLC layer (5-20 μm thick) for low friction, and a metal-free DLC layer (0.5-5 μm thick) for wear resistance. This segmentation allows each layer to optimize its specific function without compromising the others, resolving the contradiction between friction reduction and service life.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The coating uses composite material structure combining different DLC variants with distinct properties. The metal-containing DLC layer provides low friction coefficient while the metal-free DLC layer provides high wear resistance, and the adhesive layer ensures strong substrate bonding. This composite approach allows the system to achieve both low friction and long service life simultaneously.

Inventive Principle:
Principle #40Composite materials

3Loss of energy

If top layer thickness is increased to improve friction properties, then friction coefficient is reduced, but wear values deteriorate due to residual stresses

Engineering Contradiction:
Improvefriction coefficientVSAvoidwear resistance
Core Design Contradiction:
Loss of energyVSManufacturing precision

Solution Approach 1:

The coating is divided into three distinct layers: an adhesive layer (5-20 nm thick) for substrate bonding, a metal-containing DLC layer (5-20 μm thick) for low friction, and a metal-free DLC layer (0.5-5 μm thick) for wear resistance. This segmentation allows each layer to optimize its specific function without compromising the others, resolving the contradiction between friction reduction and service life.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The coating uses composite material structure combining different DLC variants with distinct properties. The metal-containing DLC layer provides low friction coefficient while the metal-free DLC layer provides high wear resistance, and the adhesive layer ensures strong substrate bonding. This composite approach allows the system to achieve both low friction and long service life simultaneously.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This coating structure achieves improved tribological properties, including reduced friction and wear, ensuring a longer service life by balancing friction and wear characteristics, with preferred hardness values and nitrogen content, and maintaining consistent performance over time.

Implementation Method 1

an adhesive layer, in particular a chromium adhesive layer

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

PVD coatings based on a hard material

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 3

a sliding element having a DLC coating with good run-in behavior

Methodology Applied
Scientific EffectPlasma Enhanced Chemical Vapour Deposition: Plasma Enhanced Chemical Vapour Deposition

Data Source

PatentUS9103442B2Sliding element, in particular a piston ring, having a coating
Publication Date: 2015.08.11 FEDERAL MOGUL BURSCHEID GMBH
  • US9103442B2 patent drawing
  • US9103442B2 patent drawing

AI summary

The invention relates to a sliding element, such as a piston ring, comprising a coating on at least one surface comprising, form inside to outside, a bonding layer, a metal DLC layer preferably containing tungsten, and a metal-free DLC layer doped with nitrogen at least in some regions, wherein said sliding element is characterized in that the nitrogen content in the metal-free DLC layer is graduated.