Piston Ring Coating Segmentation for Wear and Friction

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Solution Overview

Problem

Existing sliding element coatings, such as DLC, are inadequate for diesel or highly supercharged spark-ignition engines with iron-based cylinder liners due to low layer thickness and insufficient wear resistance and friction loss, especially under mixed friction conditions.

Innovation Solution

A combination of a CrN layer and a DLC layer, with a Me(CxNy) intermediate layer, where the DLC layer is at least partially metal-free, applied to the piston ring, enhancing wear resistance and reducing friction coefficient.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If DLC coating with low layer thickness (< 5 μm) is used, then friction loss is reduced, but wear resistance and service life are insufficient

Engineering Contradiction:
Improvefriction lossVSAvoidwear resistance
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The coating is segmented into three distinct layers: a CrN adhesive layer (5-20 μm) for strong substrate bonding, a Me(CxNy) intermediate layer (0.5-2 μm) for transition and reinforcement, and a metal-free DLC top layer (2-5 μm) for low friction. This segmentation allows each layer to optimize its specific function while working together to solve the contradiction between low friction and high wear resistance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite coating structure combining different materials: chromium nitride (CrN) for adhesive properties, metal carbonitride (Me(CxNy)) for intermediate reinforcement, and diamond-like carbon (DLC) for low friction. This composite approach integrates the advantages of each material to achieve both low friction loss and high wear resistance simultaneously.

Inventive Principle:
Principle #40Composite materials

2Duration of action of moving object

If CrN coating with increased layer thickness (10-30 μm) is applied, then service life is improved, but friction loss and wear resistance deteriorate

Engineering Contradiction:
Improveservice lifeVSAvoidfriction loss
Core Design Contradiction:
Duration of action of moving objectVSLoss of energy

Solution Approach 1:

Instead of using a single thick CrN layer, the coating is segmented where the CrN adhesive layer is limited to 5-20 μm, and the functional DLC top layer provides the low friction surface. This segmentation ensures the CrN layer provides adequate bonding and structural support without compromising the low-friction surface properties.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the coating have different thicknesses and properties optimized for their specific functions: the CrN adhesive layer at the substrate interface provides strong bonding, the Me(CxNy) intermediate layer provides transition and reinforcement, and the thin DLC top layer (2-5 μm) provides low friction. This local optimization resolves the contradiction between thickness for service life and thinness for low friction.

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If DLC layer is applied directly on substrate, then manufacturing is simplified, but adhesion and wear characteristics are insufficient

Engineering Contradiction:
Improvecoating applicationVSAvoidadhesion
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The coating system is segmented into three layers with the CrN adhesive layer serving as a dedicated bonding interface between the substrate and the DLC top layer. This segmentation ensures strong adhesion without requiring complex surface treatment or adhesive procedures, maintaining manufacturing simplicity while improving reliability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The CrN adhesive layer acts as an intermediary between the substrate and the DLC top layer, providing strong chemical bonding to the substrate while offering a suitable surface for DLC deposition. This intermediary layer ensures excellent adhesion and wear characteristics without complicating the manufacturing process.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The described layer structure significantly improves wear characteristics and reduces the relative coefficient of friction, leading to extended service life and improved tribological performance.

Implementation Method 1

The CrN layer is preferably applied to the basic piston material without an adhesive layer, for example by metal vapour deposition or sputtering.

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 2

The CrN layer is preferably applied to the basic piston material without an adhesive layer, for example by metal vapour deposition or sputtering.

Methodology Applied
Scientific EffectSputtering: Sputtering

Implementation Method 3

Due to their amorphous structure, DLC layer systems have the advantage that they are substantially chemically inactive with metal surfaces and hence have an extremely low adhesion tendency with respect to the mating running element.

Methodology Applied
Scientific EffectFriction: Friction

Data Source

PatentUS10131988B2Sliding element, in particular piston ring, and combination of a sliding element with a mating running element
Publication Date: 2018.11.20 FEDERAL MOGUL BURSCHEID GMBH
  • US10131988B2 patent drawing
  • US10131988B2 patent drawing
  • US10131988B2 patent drawing

AI summary

A sliding element, such as a piston ring, for use in diesel or highly supercharged spark-ignition engines with iron-based mating running elements is provided. The sliding element includes a base material made of cast iron or steel and a coating. The coating includes a CrN layer, an Me(CxNy) layer, and a DLC layer extending from the inside to the outer side respectively. The DLC layer consists of a metal-containing substructure layer and a metal-free DLC top layer. The Me(CxNy) layer is crystalline and Me is tungsten (W), chromium (Cr), or Silicon (Si). The hardness of the metal-free DLC top layer is harder than the metal-containing substructure layer.