Piston Ring DLC/CrN Coating for Cast Iron Adhesion and Wear

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Solution Overview

Problem

Existing surface treatments for piston rings, particularly those made of cast iron, face challenges in achieving adequate adhesion and durability of hard coatings due to the presence of graphite, leading to premature wear and loss of sealing functionality, especially when exposed to aggressive coatings like chromium or tungsten powders.

Innovation Solution

A multilayer PVD coating process involving nitriding and subsequent carbon application, combined with polishing and lapping stages, to create a firmly anchored DLC/CrN coating with enhanced hardness and wear resistance, overcoming the limitations of prior art by ensuring adhesion to spheroidal cast iron substrates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If PVD coating is applied to cast iron piston rings to increase surface hardness and wear resistance, then the coating provides better protection against wear, but the coating suffers from poor adhesion due to graphite content in cast iron

Engineering Contradiction:
Improvesurface hardnessVSAvoidcoating adhesion
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies preliminary surface preparation treatments (shot blasting, sanding, or grit blasting) to the cast iron piston ring surface before coating application. This preliminary action removes or modifies the graphite layer that causes adhesion problems, creating a suitable surface for coating adhesion while preserving the underlying cast iron substrate.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces intermediate layers between the cast iron substrate and the final PVD coating. These intermediate layers act as mediators that bond to both the prepared cast iron surface and the carbon-based PVD coating, resolving the adhesion incompatibility caused by graphite in the cast iron.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Strength

If aggressive coatings like chromium or tungsten powders are applied to piston rings to increase wear resistance, then the coating provides better protection, but premature wear occurs due to strong tribological antagonism with chromium-based cylinder coatings

Engineering Contradiction:
Improvewear resistanceVSAvoidservice life
Core Design Contradiction:
StrengthVSDuration of action of stationary object

Solution Approach 1:

The patent changes the material composition parameters of the PVD coating from traditional chromium or tungsten powders to carbon-based materials (such as amorphous carbon or diamond-like carbon). This parameter change eliminates the tribological antagonism with chromium-based cylinder coatings while maintaining or improving wear resistance properties.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process achieves a significant increase in surface hardness up to 4000 HV and improved wear resistance, ensuring the coating remains adherent and non-tensioned, effectively resisting scuffing and chipping, even in hostile engine environments.

Implementation Method 1

surface coating treatment of the outer surface of the piston rings by means of PVD (Pressure Vapor Deposition) coating

Methodology Applied
Scientific EffectPhysical Vapor Deposition: Physical Vapour Deposition

Implementation Method 2

A carbon layer is then applied to the nitrided layer

Methodology Applied
Scientific EffectNitriding: Nitriding

Data Source

PatentEP4056732A1Surface treatment of piston rings
Publication Date: 2022.09.14 ASSO WERKE SRL UNIPERSONALE
  • EP4056732A1 patent drawingFigure 1
  • EP4056732A1 patent drawingFigure 2~3A
  • EP4056732A1 patent drawingFigure 3B~3C

AI summary

The invention relates to a piston ring of an internal combustion engine which has a surface coating carried out on the contact area of the piston ring with the engine cylinder and which comprises a first outer layer of DLC with a thickness of 0.002 ± 0.001 mm and a second layer, underlying said first layer, based on chromium nitrides with a thickness of 0.014 ± 0.005 mm.