Pixel Defining Layer Outgas Reduction via Post-Heat Treatment

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Solution Overview

Problem

Organic light emitting display devices face issues with pixel shrinkage, dark spots, and reduced lifespan due to high outgas and moisture content, which affect luminance and reliability, especially when the amount of outgas is 15 ppm or more and moisture is 50 ppm or more after post-heat treatment.

Innovation Solution

A method for preparing a pixel defining layer using a photosensitive resin composition that involves prebaking, exposure, development, and post-heat treatment at 210° C. to 300° C. for 30 to 120 minutes, with the goal of minimizing outgas to 15 ppm or less and moisture to 50 ppm or less, using a colorant with an average particle diameter of 20 nm to 110 nm, and a binder resin with specific molecular weight and structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If colored patterns are used to achieve vivid colors, then color display quality is improved, but outgas amount increases causing pixel shrinkage and dark spots

Engineering Contradiction:
Improvecolor display qualityVSAvoidoutgas amount
Core Design Contradiction:
Illumination intensityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the particle size parameter of colorants to 20-110 nm range and adjusts binder resin molecular weight to 10,000-100,000, which modifies the physical state and crosslinking behavior of the colored pattern, reducing outgas generation while maintaining color quality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite photosensitive resin composition containing colorants, binder resins, and crosslinking agents that work together to achieve both vivid colors and low outgas emission through synergistic effects of the composite material system

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If colored patterns are used to achieve vivid colors, then color display quality is improved, but moisture content increases causing pixel shrinkage and electrode oxidation

Engineering Contradiction:
Improvecolor display qualityVSAvoidmoisture content
Core Design Contradiction:
Illumination intensityVSObject-generated harmful factors

Solution Approach 1:

The patent modifies the molecular weight parameter of binder resin to 10,000-100,000 and adjusts crosslinking density, which changes the moisture absorption characteristics and enhances moisture removal efficiency during post-heat treatment, reducing moisture content to 50 ppm or less

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a crosslinked network structure that acts as a barrier to moisture penetration, effectively creating an inert environment within the colored pattern that prevents external moisture absorption and internal moisture-related damage

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

3Reliability

If post-heat treatment is performed to remove moisture and outgas, then reliability is improved, but process time and energy consumption increase

Engineering Contradiction:
Improvedisplay reliabilityVSAvoidpost-heat treatment time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent performs prebaking before the main post-heat treatment process to remove a portion of moisture and volatile organic compounds in advance, which reduces the burden on the subsequent post-heat treatment step and shortens the overall processing time while maintaining reliability

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent designs the photosensitive resin composition to enable continuous moisture and outgas removal throughout the drying and curing processes, maintaining effective outgas venting and moisture removal throughout the entire post-heat treatment period rather than requiring extended treatment times

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach ensures vivid colors, increased display reliability, and extended lifespan by minimizing outgas and moisture, thereby preventing pixel shrinkage and dark spots, and enhancing the overall performance of the organic light emitting display device.

Implementation Method 1

a photosensitive resin composition is used, which has a crosslinking structure during a development process

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

the moisture is removed through the post-heat treatment process

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS20250093776A1Method for preparing pixel defining layer
Publication Date: 2025.03.20 DUK SAN NEOLUX
  • US20250093776A1 patent drawing
  • US20250093776A1 patent drawing
  • US20250093776A1 patent drawing

AI summary

The present disclosure is not only to ensure vivid colors but also to increase display reliability and lifespan by implementing a colored pattern with low outgas amount and moisture content on an electrode substrate; in other words, since it may cause a decrease in luminance and a decrease in lifespan due to pixel shrinkage if the amount of outgas in the panel after post-heat treatment is 15 ppm or more, or the moisture content is 50 ppm or more, the present disclosure is to minimize the generation of outgas and the moisture content in the panel state by maintaining sufficient heat and time and generating sufficient fume in the post-heat treatment step in order to minimize the outgas amount and moisture content after completing the post-heat treatment process by including a colorant according to the present disclosure.