Planar Mica Hydrogen Sensor for Vibration Robustness

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Solution Overview

Problem

Traditional catalytic combustion-type hydrogen sensors with filament structures are prone to failure due to brittleness and complexity in manufacturing, limiting their application in vehicle-mounted environments, where they require improved robustness and cost-effectiveness.

Innovation Solution

A catalytic combustion-type hydrogen sensor with a planar structure using ultra-thin mica sheets as substrates and a platinum resistor, manufactured via magnetron sputtering and mask techniques, which replaces the complex micro-electromechanical system (MEMS) technology, ensuring mechanical flexibility, high-temperature resistance, and low specific heat capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a filament structure is used in traditional catalytic combustion-type hydrogen sensors, then the sensor can achieve hydrogen detection function, but the sensor is prone to failure due to brittleness and filament breakage under vehicle-mounted vibration conditions

Engineering Contradiction:
Improvesensor reliabilityVSAvoidfilament strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The filament structure is segmented into a planar bridge structure composed of multiple connected segments (substrate, bridge body, and working electrode layer), distributing mechanical stress and preventing catastrophic failure from single-point breakage

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The traditional mechanical filament structure is replaced with a planar MEMS bridge structure that uses thermal and electrical fields for sensing, reducing mechanical brittleness while maintaining detection function

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Use of energy by moving object

If MEMS planar structure with ultra-thin bridge body is used to reduce heat capacity, then sensing performance is improved, but the device robustness and fabrication consistency deteriorate due to ultra-thin structural characteristic and silicon-based material brittleness

Engineering Contradiction:
Improveheat capacityVSAvoiddevice robustness
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The device uses a composite structure combining silicon substrate with silicon oxide or silicon nitride bridge body, leveraging the mechanical strength of silicon while using the lower thermal conductivity and appropriate specific heat capacity of oxide/nitride layers for optimal thermal response

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The bridge body is constructed as a thin film structure with controlled thickness (1-10 micrometers) that provides flexibility and low heat capacity while maintaining structural integrity through the film's continuous structure and adherence to substrate

Inventive Principle:
Principle #30Flexible shells and thin films

3Device complexity

If MEMS manufacturing process is used to create planar catalytic combustion sensor, then device structure is miniaturized and robustness is improved, but the manufacturing process becomes complicated and cost increases

Engineering Contradiction:
Improvedevice structureVSAvoidmanufacturing process
Core Design Contradiction:
Device complexityVSEase of manufacture

Solution Approach 1:

The planar bridge structure serves multiple functions simultaneously: mechanical support, thermal management, and sensing platform, eliminating the need for separate filament components and simplifying the overall manufacturing process

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The bridge body thickness is optimized to a specific range (1-10 micrometers) that balances low heat capacity for fast response with sufficient mechanical strength for robustness, achieving optimal performance without requiring ultra-thin fabrication

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a stable, cost-effective, and robust hydrogen sensor capable of withstanding vibrations, maintaining performance after repeated bending, and optimizing the use of palladium nanoparticles for enhanced hydrogen detection.

Implementation Method 1

manufactured via magnetron sputtering and mask techniques

Methodology Applied
Scientific EffectMagnetron sputtering: Sputtering

Implementation Method 2

catalytic combustion type hydrogen sensor

Methodology Applied
Scientific EffectCatalytic combustion: Catalysis

Implementation Method 3

catalytic combustion element is configured to detect a concentration of hydrogen

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentUS20240345013A1Catalytic combustion type hydrogen sensor and manufacturing method therefor
Publication Date: 2024.10.17 ZHEJIANG UNIV OF TECH
  • US20240345013A1 patent drawing
  • US20240345013A1 patent drawing
  • US20240345013A1 patent drawing

AI summary

Disclosed in the present disclosure are a catalytic combustion type hydrogen sensor and a manufacturing method therefor. The catalytic combustion type hydrogen sensor includes a catalytic combustion element and a compensation element, where both the catalytic combustion element and the compensation element are planar film structures taking mica sheets as substrates, and platinum resistors and aluminum oxide film carriers are sequentially adhered on surfaces of the mica sheets. A layer of palladium nanoparticles are further adhered to a surface of the aluminum oxide film carrier of the catalytic combustion element as a catalyst. According to the present disclosure, the ultra-thin mica sheet is used for replacing a silicon-based material to manufacture the film type catalytic combustion type hydrogen sensor, such that a complicated and high-cost micro-electromechanical system (MEMS) technology is avoided, and the flexible characteristic of the ultra-thin mica sheet endows the sensor with extremely high robustness.