Plant-Derived Polythiol Composition for Low-Haze Optical Materials

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Solution Overview

Problem

Optical materials produced from existing polymerizable compositions containing plant-derived compounds exhibit high haze and require improvements in optical properties.

Innovation Solution

A polythiol is obtained by thiolating the hydroxy groups of plant-derived polyols, which is then reacted with polyiso(thio)cyanate to form a polymerizable composition for optical materials, resulting in a cured optical material with improved optical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If plant-derived polyol is used in polymerizable composition for optical materials, then non-fossil resource utilization is improved, but haze increases and optical properties deteriorate

Engineering Contradiction:
Improvenon-fossil resource utilizationVSAvoidhaze
Core Design Contradiction:
Adaptability or versatilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameter of the polyol by converting hydroxy groups to thiol groups through thiolation reaction. This parameter change transforms plant-derived polyol into polythiol, which maintains the benefit of non-fossil resource utilization while eliminating the harmful haze effect in the cured optical material.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the harmful effect of using plant-derived polyol (which causes high haze) into a beneficial outcome by chemically transforming it into polythiol. The thiolation process converts the problematic hydroxy groups into thiol groups, turning the originally harmful plant-derived compound into a beneficial component that provides both sustainability and excellent optical properties.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Adaptability or versatility

If existing polymerizable composition containing plant-derived compound is used, then sustainability is improved, but manufacturing precision of optical properties deteriorates

Engineering Contradiction:
ImprovesustainabilityVSAvoidoptical properties
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The patent applies thiolation reaction to change the chemical structure of plant-derived polyol, converting hydroxy groups to thiol groups. This parameter change in the molecular structure enables the material to achieve precise control over optical properties while maintaining sustainability benefits.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces thiolation reaction as an intermediary process between obtaining plant-derived polyol and using it in the polymerizable composition. This intermediary chemical transformation step is crucial for converting the raw plant-derived material into a form that delivers precise optical properties in the final cured product.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces optical materials with reduced haze and enhanced optical clarity, utilizing plant-derived materials for sustainable resource utilization.

Implementation Method 1

a polythiol obtained through a thiolation of a hydroxy group of a plant-derived polyol

Methodology Applied
Scientific EffectThiolation: Chemical Bonding

Implementation Method 2

A polymerizable composition for optical materials, including: at least one polythiol as in [1] or [2]; and at least one polyiso(thio)cyanate

Methodology Applied
Scientific EffectPolymerization: Chemical Bonding

Data Source

PatentEP4692053A1Polythiol, polymerizable composition for optical materials, optical material, and methods for producing those products
Publication Date: 2026.02.11 HOYA LENS THAILAND LTD
  • EP4692053A1 patent drawing
  • EP4692053A1 patent drawing
  • EP4692053A1 patent drawing

AI summary

Provided is a polythiol obtained through a thiolation of a hydroxy group of a plant-derived polyol.