Potassium-Rich Plant Catalyst for Organic Synthesis

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Solution Overview

Problem

Existing methods for obtaining catalysts for organic synthesis reactions often involve high environmental impact due to thermal and basic/acid treatments, and are unable to facilitate difficult reactions.

Innovation Solution

A composition comprising K2CO3, KCl, and optionally K2SO4 and/or KHCO3, with a potassium weight content between 9.0 and 60.0%, obtained from plants with high potassium content through a heat treatment process, is used as a catalyst for organic synthesis reactions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional chemical processes are used to obtain basic compounds for organic synthesis, then the reactions can be implemented, but the environmental impact is high due to thermal and basic/acid treatments

Engineering Contradiction:
Improvecatalyst preparationVSAvoidenvironmental impact
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The invention changes the chemical composition parameters by using potassium-rich plant extracts containing potassium carbonate, potassium chloride, and potassium sulfate instead of conventional catalysts requiring thermal and basic/acid treatments. This compositional change eliminates the need for harmful treatment steps while maintaining catalytic activity for organic synthesis reactions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses readily available plant materials as catalyst precursors that can be processed into active catalysts without complex preparation. The plant-based catalysts are inexpensive, easily obtainable, and can be used in a single-use or limited-life manner, eliminating the need for complex regeneration or recovery processes associated with conventional catalysts

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Productivity

If conventional catalysts are used for difficult organic reactions, then the reactions can proceed under standard conditions, but the reactions remain difficult to implement

Engineering Contradiction:
Improvereaction efficiencyVSAvoidreaction implementation
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The invention changes the catalytic parameters by introducing potassium-rich plant extracts that provide a unique combination of potassium salts (carbonate, chloride, sulfate) acting synergistically as catalysts. This compositional change enables difficult organic reactions to proceed under milder conditions with improved efficiency and ease of implementation compared to conventional catalysts

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If thermal treatments at high temperature are applied to transform calcium compounds, then the catalyst can be obtained, but the energy balance increases

Engineering Contradiction:
Improvecatalyst synthesisVSAvoidenergy balance
Core Design Contradiction:
Ease of manufactureVSUse of energy by moving object

Solution Approach 1:

The invention replaces energy-intensive thermal treatment processes with a simple extraction and drying process using potassium-rich plant materials. The plant extracts are processed at low temperatures to obtain the active catalyst, eliminating the need for high-temperature calcination steps required by conventional calcium-based catalyst synthesis

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention changes the synthesis parameters by using plant-based potassium sources that require only mild thermal processing for activation, rather than the high-temperature treatment needed for calcium compound transformation. This parameter change dramatically reduces energy consumption while maintaining catalyst effectiveness

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively catalyzes various organic reactions with reduced environmental impact, including those difficult to implement with conventional catalysts, and allows for the implementation of organic syntheses under milder conditions.

Implementation Method 1

starting from plants wherein the above-ground parts comprise a very high amount potassium, they were able to obtain a composition according to the invention. Preferably, the composition according to the invention is a polymetallic composition.

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Implementation Method 2

these natural materials undergo several thermal and basic/acid treatments. Around 550° C., calcium oxalates comprised in the plants are transformed into calcium carbonates, and around 800° C., calcium carbonates are transformed into calcium oxides.

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Data Source

PatentUS20250121362A1Novel compositions for the sustainable catalysis of organic synthesis reactions
Publication Date: 2025.04.17 CENT NAT DE LA RECH SCI (C N R S)
  • US20250121362A1 patent drawing
  • US20250121362A1 patent drawing
  • US20250121362A1 patent drawing

AI summary

A composition comprising K2CO3, KCl, and optionally K2SO4 and/or KHCO3, having a weight content of potassium between 9.0 and 60.0% relative to the total weight of the composition, preferably between 10.0 and 50.0%, more preferably between 10.0 and 40.0%, advantageously between 20.0 and 40.0%.