Plant Protein Microcapsules via Aliphatic Polyisocyanate Crosslinking

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Solution Overview

Problem

Existing microencapsulation technologies face challenges in achieving biodegradability and stability while maintaining effective release properties for hydrophobic active ingredients, particularly in consumer products where environmental impact and veganism are concerns.

Innovation Solution

The development of plant protein-based microcapsules produced through an aqueous emulsion process using aliphatic polyisocyanates as crosslinking agents, which form a stable capsule shell for encapsulating hydrophobic active ingredients while being biodegradable and vegan-friendly.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional microencapsulation technologies are used to achieve stability, then the capsule shell provides good stability, but biodegradability and environmental impact are compromised

Engineering Contradiction:
Improvecapsule shell stabilityVSAvoidenvironmental impact
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the capsule shell by using plant protein-based polymers instead of conventional synthetic polymers. This substitution maintains the structural integrity and stability needed for encapsulation while introducing biodegradability and reducing environmental harm, directly resolving the contradiction between stability and environmental impact

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structures by combining plant protein-based polymers with crosslinking agents to create a capsule shell that achieves both stability and biodegradability. The composite approach allows the shell to maintain mechanical strength through crosslinking while the plant protein base ensures biodegradability, simultaneously addressing both requirements

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If plant protein-based microcapsules are produced to achieve biodegradability, then environmental impact is reduced, but stability and release properties may be compromised

Engineering Contradiction:
Improveenvironmental impactVSAvoidcapsule shell stability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent modifies the physical and chemical parameters of the plant protein-based polymer through controlled crosslinking. By adjusting crosslinking density and degree, the shell achieves optimal balance between stability for encapsulation and biodegradability for environmental compatibility, resolving the contradiction between these two properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies partial crosslinking rather than complete crosslinking of the plant protein-based polymer. This partial action maintains sufficient stability for encapsulation while leaving enough uncrosslinked regions to allow biodegradation, effectively resolving the contradiction between stability and environmental impact

Inventive Principle:
Principle #16Partial or excessive action

3Reliability

If a stable capsule shell is formed for hydrophobic active ingredients, then encapsulation efficiency is improved, but release properties may be compromised

Engineering Contradiction:
Improveencapsulation efficiencyVSAvoidrelease properties
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The patent creates local quality variations in the capsule shell by forming regions with different crosslinking densities. Some regions have higher crosslinking for stability and encapsulation, while other regions have lower crosslinking to facilitate controlled release of hydrophobic active ingredients, resolving the contradiction between encapsulation efficiency and release properties

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent applies partial crosslinking to achieve a balance between stability and release. By not fully crosslinking the plant protein-based polymer, the shell maintains sufficient stability for encapsulation while retaining enough flexibility and porosity to allow controlled release of the active ingredient over time

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The plant protein-based microcapsules demonstrate excellent stability and sensory performance, with improved biodegradability and reduced environmental impact, making them suitable for a wide range of applications including household products and cosmetics.

Implementation Method 1

The plant protein-based microcapsules are produced by interfacial polymerization of a plant protein with aliphatic polyisocyanates

Methodology Applied
Scientific EffectInterfacial polymerization: Chemical Bonding

Implementation Method 2

aliphatic polyisocyanates as crosslinking agents, which form a stable capsule shell

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 3

The plant protein-based microcapsules are produced by interfacial polymerization in an aqueous emulsion

Methodology Applied
Scientific EffectEmulsion: Emulsion

Data Source

PatentUS20250144589A1Method for Producing Microcapsules
Publication Date: 2025.05.08 SYMRISE GMBH & CO KG
  • US20250144589A1 patent drawing
  • US20250144589A1 patent drawing
  • US20250144589A1 patent drawing

AI summary

The present invention relates to a process for the preparation of microcapsules, in particular plant protein-based microcapsules and dispersions of such microcapsules (microcapsule slurry), which include at least one hydrophobic active ingredient, preferably perfume- or aroma-containing plant protein-based microcapsules, which have a balance of stability and performance compared to microcapsules of the prior art. Furthermore, the present invention relates to plant protein-based microcapsules obtainable by the method according to the invention. In a further aspect, the present invention relates to the use of the plant protein-based microcapsules and dispersions according to the invention as a component of household products, textile care products, detergents, fabric softeners, cleaning agents, scent boosters or fragrance enhancers in liquid or solid form, cosmetics, personal care products, perfume compositions, agricultural products, pharmaceutical products or print coating for paper. Ultimately, the present invention relates to consumer products comprising such microcapsules or microcapsule dispersions according to the invention.