Plasma Carbon Black Surface Functionalization for Rubber Performance

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing carbon black production methods, particularly plasma processes, lack the ability to control surface functionalization, resulting in unoptimized performance for specific applications due to the absence of oxygen-containing functional groups, which are inherently formed in traditional furnace processes.

Innovation Solution

A method to control the surface functionalization of carbon black particles by introducing specific functional groups through controlled exposure to oxidizing agents, temperature, and pressure conditions in the reactor, pelletizer, and dryer, allowing for tailored surface chemistry to meet application-specific requirements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If plasma process is used to produce carbon black, then production efficiency and yield are improved, but surface functionalization is uncontrolled and oxygen-containing functional groups are absent

Engineering Contradiction:
Improveproduction efficiencyVSAvoidsurface functionalization control
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent introduces oxygen-containing functional groups to the carbon black surface during the plasma production process itself, rather than as a subsequent step. By incorporating oxidizing agents into the plasma environment or using oxygen-containing gases in the plasma chamber, the surface functionalization is established preliminarily during formation, achieving both high productivity and controlled surface chemistry.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent modifies plasma process parameters by introducing oxygen-containing species into the plasma environment. This includes adjusting gas composition to include oxygen, using oxygen-containing radicals in the plasma, or controlling the energy distribution to favor oxygen incorporation. These parameter changes enable controlled surface functionalization while maintaining the high efficiency of plasma production.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If traditional furnace process is used, then oxygen-containing functional groups are formed, but production efficiency and yield are reduced

Engineering Contradiction:
Improvesurface functionalizationVSAvoidproduction efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent replaces the thermal oxidation mechanism of traditional furnace processes with a plasma-based chemical activation system. Instead of relying on high-temperature combustion to form functional groups, the invention uses plasma-generated reactive species and controlled oxygen incorporation to achieve surface functionalization at lower temperatures, thereby maintaining high production efficiency while achieving the desired surface chemistry.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If surface functionalization is increased to improve rubber compound performance, then bound rubber content and fuel efficiency are enhanced, but manufacturing equipment wear increases

Engineering Contradiction:
Improverubber compound performanceVSAvoidequipment wear
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent employs controlled oxidation through plasma-generated reactive oxygen species and oxygen-containing functional groups. By using this accelerated oxidation mechanism, the surface functionalization is achieved more efficiently and at lower temperatures than conventional methods, reducing thermal stress and mechanical wear on equipment while enhancing rubber compound performance through improved bound rubber content and fuel efficiency.

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the production of carbon black with optimized surface chemistry, enhancing performance in rubber compounds by improving properties such as bound rubber content, reducing vibration, and increasing vehicle fuel efficiency.

Implementation Method 1

the functionalizing agents contain one or more oxidizing agents

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

A method of making carbon black in a plasma process is described

Methodology Applied
Scientific EffectPlasma: Plasma

Data Source

PatentUS12497517B1Method of making carbon black
Publication Date: 2025.12.16 MONOLITH MATERIALS INC
  • US12497517B1 patent drawing

AI summary

A method of making tailored carbon black in a plasma process. A method of making tailored carbon black in a plasma process is described, including subjecting the carbon black particles during and/or after formation to surface functionalizing agents in a controlled manner so as to impart a degree and/or density of functionalization onto the carbon black particles so as to adapt the particles to a particular pre-intended application.