Plasma Chlorine Replacement in Thin Film Transistors

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Solution Overview

Problem

Chlorine residuals from plasma etching processes corrode surfaces and can cause re-etching, affecting the electric properties of thin film transistors and increasing manufacturing time.

Innovation Solution

A method involving a reduced volume ratio of fluorine-bearing gases to oxygen gases in a plasma process to minimize ionic concentration, replacing chlorine atoms on film layers while avoiding re-etching and reducing processing time.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If fluorine-bearing gas is used in plasma process to replace chlorine atoms, then corrosion prevention is improved, but re-etching occurs affecting electric properties

Engineering Contradiction:
Improvecorrosion preventionVSAvoidre-etching
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the concentration parameter of fluorine-bearing gas from the conventional 1/10 to 1/6 ratio to a reduced ratio of 1/20 to 1/10. This parameter adjustment reduces the ionic concentration of fluorine in the plasma, preventing re-etching of the film layer while maintaining sufficient fluorine ions for chlorine atom replacement and corrosion prevention.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If pure oxygen plasma process is used to replace chlorine atoms, then re-etching is avoided, but manufacturing time increases

Engineering Contradiction:
Improvere-etching preventionVSAvoidmanufacturing time
Core Design Contradiction:
Object-affected harmful factorsVSLoss of time

Solution Approach 1:

The patent introduces fluorine-bearing gas at a reduced concentration ratio (1/20 to 1/10) to enhance the replacement efficiency of chlorine atoms compared to pure oxygen process. This allows the manufacturing time to be reduced from the conventional 30-45 seconds while still preventing re-etching, as the optimized fluorine ion concentration accelerates the chlorine removal process.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively prevents corrosion and re-etching, preserves the electric properties of thin film transistors, and reduces manufacturing time compared to conventional methods, thereby enhancing production yield and efficiency.

Implementation Method 1

dissociating the gas mixture through a plasma process to form an ionic mixture

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

dissociating the gas mixture through a plasma process to form an ionic mixture

Methodology Applied
Scientific EffectIonization: Ionisation

Implementation Method 3

bombarding the ionic mixture onto a surface of the film layer, causing the chlorine atoms through a reaction to be replaced

Methodology Applied
Scientific EffectIon bombardment: Ion Beam

Implementation Method 4

causing the chlorine atoms through a reaction to be replaced by one type of ions of the ionic mixture

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS8785331B2Method for replacing chlorine atoms on a film layer
Publication Date: 2014.07.22 TCL CHINA STAR OPTOELECTRONICS TECHNOLOGY CO LTD
  • US8785331B2 patent drawing
  • US8785331B2 patent drawing

AI summary

The present invention discloses a method for replacing chlorine atoms on a film layer. More particularly, sufficient replacement ions for replacing the chlorine atoms are formed in a plasma process by reducing a volume ratio of a gas in a gas mixture (i.e. the film layer may be etched with the ions formed by dissociation of the gas) and dissociation of the gas mixture further decreases the etching reaction to the film layer in a process for replacing the chlorine atoms. In comparison to a conventional process by pure oxygen, the present invention can improve the prior art re-etching problem to avoid affecting an electric property of a thin film transistor, also has an advantage of manufacturing time reduction for an increased production yield.