Plasma Etchant Composition Control for SiGe Selective Substrate Processing

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Solution Overview

Problem

Existing semiconductor fabrication processes face challenges in maintaining consistent etching selectivity and process control, particularly when dealing with materials like silicon germanium, which requires high etching selectivity and precise control over critical dimensions.

Innovation Solution

A substrate processing apparatus and method that utilizes a combination of first and second etchants generated from plasma, with real-time composition rate monitoring and feedback control mechanisms to ensure consistent process performance through a look-up table and process parameter adjustments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional etching processes are used for silicon germanium (SiGe) sacrificial film, then etching can be performed, but etching selectivity with respect to silicon (Si) is insufficient

Engineering Contradiction:
Improveetching selectivityVSAvoidprocess consistency
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the etchant by using a mixed etchant system comprising HF (hydrofluoric acid) and H2SO4 (sulfuric acid) in specific ratios. By adjusting the concentration and ratio of these chemicals, the etching selectivity between SiGe and Si is optimized while maintaining process consistency across repeated operations.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite etchant solution combining HF and H2SO4 in specific proportions. This composite chemical system leverages the complementary properties of both acids: HF for etching silicon-based materials and H2SO4 for enhancing selectivity and controlling etching rate, achieving superior SiGe/Si selectivity compared to single-chemical etchants.

Inventive Principle:
Principle #40Composite materials

2Productivity

If etching process is repeated multiple times, then production efficiency is improved, but process performance consistency deteriorates due to variations in etching rate and critical dimension control

Engineering Contradiction:
Improveproduction efficiencyVSAvoidprocess performance consistency
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent implements a feedback control mechanism where process parameters such as etchant composition, temperature, and exposure time are continuously monitored and adjusted based on measured etching results. This closed-loop control ensures that even when the process is repeated multiple times, the etching selectivity and critical dimension control remain consistent across all batches.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent performs preliminary optimization of the etching process by establishing precise etchant composition ratios and process parameters before production begins. This pre-characterization of the etching system allows for consistent reproduction of results across multiple processing runs, maintaining manufacturing precision while enabling high productivity.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If high etching selectivity is achieved for SiGe, then desired pattern formation is enabled, but etching rate control becomes more difficult

Engineering Contradiction:
Improvepattern formation accuracyVSAvoidetching rate control
Core Design Contradiction:
Manufacturing precisionVSSpeed

Solution Approach 1:

The patent achieves both high etching selectivity and controlled etching rate by optimizing multiple parameters simultaneously: the HF:H2SO4 ratio in the etchant, the absolute concentrations of each chemical, the etching temperature, and the exposure time. This multi-parameter optimization allows the process to achieve high SiGe/Si selectivity while maintaining predictable and controllable etching rates for precise pattern formation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Ensures consistent etching selectivity and process control by dynamically adjusting process parameters based on etchant composition, maintaining high precision and reliability in semiconductor fabrication.

Implementation Method 1

generating a process etchant from the process gas using plasma ignition, the process etchant including a first etchant and a second etchant

Methodology Applied
Scientific EffectPlasma ignition: Plasma

Data Source

PatentUS12610772B2Substrate processing apparatus, substrate processing method and method of fabricating semiconductor device
Publication Date: 2026.04.21 SAMSUNG ELECTRONICS CO LTD
  • US12610772B2 patent drawing
  • US12610772B2 patent drawing
  • US12610772B2 patent drawing

AI summary

A method of fabricating a semiconductor device is provided. The method includes: loading a substrate into a substrate processing apparatus; and processing the substrate, using the substrate processing apparatus. The processing the substrate includes: providing a process gas; generating a process etchant from the process gas, using plasma ignition, the process etchant including a first etchant and a second etchant; processing the substrate, using the process etchant; identifying a composition rate of the process etchant; and controlling the processing of the substrate based on a process result according to the composition rate of the process etchant.