Plasma Etching Method for High Aspect Ratio Contact Holes

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Solution Overview

Problem

Conventional plasma etching methods face challenges in forming high aspect ratio contact holes in semiconductor devices while preventing bowing and maintaining vertical sidewall shapes.

Innovation Solution

A plasma etching method involving a two-step process using gases with varying C/F ratios, where the first process uses a gas with a higher C/F ratio for deposition and the second process uses a gas with a lower C/F ratio to control residual mask amounts and suppress bowing, ensuring a vertical sidewall shape.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Length of moving object

If a plasma etching method using a single processing gas is employed to form high aspect ratio contact holes, then the etching depth can be increased, but the sidewall shape becomes non-vertical and bowing occurs

Engineering Contradiction:
Improveetching depthVSAvoidsidewall shape
Core Design Contradiction:
Length of moving objectVSShape

Solution Approach 1:

The plasma etching process is divided into multiple steps, each using a different processing gas with specific C/F ratio characteristics. The first step uses a gas with higher C/F ratio for initial etching, and subsequent steps use gases with lower C/F ratios to correct sidewall shape and reduce bowing, achieving both deep etching and vertical sidewalls

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The C/F ratio of the processing gas is systematically changed throughout the etching process. By adjusting the carbon to fluorine ratio in different etching steps, the patent controls the deposition and etching behavior to maintain vertical sidewalls while achieving high aspect ratio contact holes

Inventive Principle:
Principle #35Parameter changes

2Productivity

If a processing gas with high deposition property is used to etch the substrate, then the etching rate increases, but excessive deposition occurs on the mask layer causing bowing

Engineering Contradiction:
Improveetching rateVSAvoidmask layer shape
Core Design Contradiction:
ProductivityVSShape

Solution Approach 1:

The patent changes the C/F ratio parameter of the processing gas between different etching steps. The first step uses a gas with higher C/F ratio for efficient etching, while subsequent steps use gases with lower C/F ratios to minimize deposition on the mask layer and prevent bowing, thus controlling both etching rate and deposition

Inventive Principle:
Principle #35Parameter changes

3Shape

If a processing gas with low deposition property is used to etch the substrate, then mask layer protection is improved, but the etching rate decreases making high aspect ratio formation difficult

Engineering Contradiction:
Improvemask layer integrityVSAvoidetching rate
Core Design Contradiction:
ShapeVSProductivity

Solution Approach 1:

The etching process is segmented into multiple steps with different gas compositions. Early steps use gases optimized for high etching rates, while later steps use gases with lower deposition properties to protect the mask layer and refine the sidewall shape, combining the benefits of both high productivity and mask protection

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively forms high aspect ratio contact holes with reduced bowing and maintains vertical sidewall integrity by adjusting the C/F ratios of the etching gases, enhancing etching selectivity and preventing excessive deposition.

Implementation Method 1

a plasma etching process using a processing gas including a first processing gas containing carbon (C) and fluorine (F)

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

etching the substrate by using plasma of a gas having a low deposition property

Methodology Applied
Scientific EffectChemical reactions: Chemical Bonding

Implementation Method 3

a process of forming a protection film by using plasma of a gas having a high deposition property

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS8679358B2Plasma etching method and computer-readable storage medium
Publication Date: 2014.03.25 TOKYO ELECTRON LTD
  • US8679358B2 patent drawing
  • US8679358B2 patent drawing
  • US8679358B2 patent drawing

AI summary

A plasma etching method includes a preparation process for performing a plasma etching process using a processing gas including a first processing gas containing carbon (C) and fluorine (F), a ratio (C/F) of the first processing gas having a first value, and obtaining a residual amount of the mask layer corresponding to a variation point where a variation amount of the bowing CD is increased; a first plasma etching process using the processing gas including the first processing gas until a residual amount of the mask layer reaches the variation point; and a second plasma etching process performed after the first plasma etching process. The second plasma etching process is performed by using a processing gas including at least a second processing gas containing carbon (C) and fluorine (F), and a ratio (C/F) of the second processing gas is smaller than the first value.