Two-Stage Plasma Etching for Silicon Film Selectivity

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Solution Overview

Problem

Existing etching methods face challenges in achieving high etch selectivity when processing silicon-containing films using masks made of amorphous carbon or organic polymers.

Innovation Solution

An etching method involving two stages: initial etching with hydrogen fluoride gas to form a recess without exposing the underlying film, followed by a second etching stage using a different process gas and conditions to further etch the silicon-containing film, including controlling temperature and pressure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a single etching process is used to etch the silicon-containing film, then the etching rate is maintained, but the etch selectivity deteriorates causing the underlying film to be exposed

Engineering Contradiction:
Improveetch selectivityVSAvoidetching process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The etching process is divided into two distinct stages: a first etching process that etches the silicon-containing film without exposing the underlying film, and a second etching process that continues etching under different conditions. This segmentation allows optimization of etch selectivity at each stage, preventing premature exposure of the underlying film while maintaining overall etching efficiency.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The etching process dynamically adjusts parameters between two stages: the first etching process uses specific plasma conditions to achieve high selectivity, and when a predetermined condition is met (such as when the etching depth reaches a threshold), the process transitions to a second etching process with different parameters. This dynamic adjustment maintains optimal etch selectivity throughout the entire etching sequence.

Inventive Principle:
Principle #15Dynamics

2Manufacturing precision

If the etching continues until the underlying film is fully exposed, then the etching completeness is improved, but the manufacturing precision deteriorates due to loss of selectivity

Engineering Contradiction:
Improveetching completenessVSAvoidunderlying film protection
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The etching process incorporates feedback control by monitoring predetermined conditions during the first etching process. When the monitoring indicates that continuing the first etching process would expose the underlying film, the system automatically transitions to the second etching process. This feedback mechanism ensures the silicon-containing film is completely etched while protecting the underlying film from damage.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The method performs preliminary etching action in the first etching process to remove the majority of the silicon-containing film while maintaining high selectivity. By preparing the structure in advance and stopping before the underlying film is exposed, the second etching process can then complete the removal with appropriate parameter adjustments, ensuring complete etching without compromising the underlying film.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Improves etch selectivity by selectively etching the silicon-containing film without exposing the underlying film, enhancing precision and control in semiconductor manufacturing.

Implementation Method 1

etching the silicon-containing film to form a recess with first plasma generated from a first process gas containing a hydrogen fluoride gas

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

etching the silicon-containing film with first plasma generated from a first process gas containing a hydrogen fluoride gas

Methodology Applied
Scientific EffectChemical reactions: Chemical Bonding

Data Source

PatentUS12532681B2Etching method and plasma processing system
Publication Date: 2026.01.20 TOKYO ELECTRON LTD
  • US12532681B2 patent drawing
  • US12532681B2 patent drawing
  • US12532681B2 patent drawing

AI summary

A technique improves etch selectivity. An etching includes (a) providing, in a chamber, a substrate including an underlying film and a silicon-containing film on the underlying film, (b) etching the silicon-containing film to form a recess with first plasma generated from a first process gas containing a hydrogen fluoride gas until before the underlying film is exposed at the recess or until the underlying film is partly exposed at the recess, and (c) further etching the silicon-containing film at the recess under a condition different from a condition of (b).