Plasma-Etching Irregular Surfaces Using Partly Oxidized Metal Salt Film Resist

Solution Overview

Problem

Conventional methods for forming metal oxide films on substrates with concave-convex structures are inefficient, requiring multiple steps and struggling with stability and precision, especially in forming conductive layers for electronic devices like organic solar cells.

Innovation Solution

A plasma-etching process using a partly oxidized metal salt film with a fine irregular surface as a resist to adjust etching speed, allowing for the stable and precise formation of large irregular surfaces on substrates, which can then be used to create electrode components with improved conductivity and light scattering properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a metal oxide film is formed on a substrate with concave-convex structure using conventional methods, then the film formation is attempted, but the process requires multiple steps and lacks stability and precision

Engineering Contradiction:
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention changes the surface energy parameter of the substrate by applying a plasma treatment before metal oxide film formation. This parameter change enables direct film formation on concave-convex structures without requiring multiple preparatory steps, thereby improving precision while reducing process complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The plasma treatment is applied as a preliminary action to modify the substrate surface properties before metal oxide deposition. This preliminary surface activation enables subsequent direct film formation on irregular surfaces, eliminating the need for multiple intermediate steps and improving overall process efficiency

Inventive Principle:
Principle #10Preliminary action

2Manufacturing precision

If a plasma-etching process is used to form irregular surfaces, then surface roughness can be controlled, but the etching speed must be precisely adjusted for stability

Engineering Contradiction:
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The invention implements a feedback mechanism where the plasma etching process parameters are dynamically adjusted based on real-time monitoring of etching rate and surface morphology. This feedback control ensures stable etching speed while maintaining precise control over the resulting surface roughness, resolving the contradiction between precision and reliability

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the formation of substrates with controlled surface roughness and conductivity, suitable for electronic devices, enhancing their performance and reducing production costs by simplifying the process and improving the stability of the metal oxide films.

Implementation Method 1

a plasma-etching process (plasma treatment)

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

a partly oxidized metal salt film having a fine irregular surface

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS9054244B2Irregular-surface forming method using plasma-etching process, and electrode member
Publication Date: 2015.06.09
  • US9054244B2 patent drawing
  • US9054244B2 patent drawing
  • US9054244B2 patent drawing

AI summary

A method is provided forming a predetermined irregular-surface pattern on a substrate. The method includes carrying out a plasma-etching process using a partly oxidized metal salt film having fine irregular-surface as a resist. In a first step, a metal salt film is formed on the substrate by coating a liquid material containing a metal salt. In a second step, a fine irregular-surface is formed on the metal salt film, and the metal salt film was converted into the resist by the partial oxidization. In a third step, a predetermined irregular-surface is formed on the substrate by carrying out the plasma-etching process to the substrate with the resist.