Plasma Extraction of Metallic Species from Electronic Waste

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Solution Overview

Problem

Current recycling technologies, such as hydrometallurgy and pyrometallurgy, face challenges in efficiently extracting metals from electronic waste due to variable composition, high energy consumption, and inconsistent purity, making them unsuitable for processing complex alloys found in electronic waste.

Innovation Solution

A process involving plasma injection into an extraction chamber, where the plasma forms and excites molecules at the surface of the matrix, allowing for continuous monitoring and selective extraction of desired metallic species through real-time adjustment of plasma parameters, ensuring high purity and adaptability to varying compositions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If hydrometallurgy is used to extract metals from electronic waste, then metallic species can be extracted from the matrix, but the process is not adaptable to variable composition and requires complex chemical operations

Engineering Contradiction:
Improvemetallic species extractionVSAvoidadaptability to variable composition
Core Design Contradiction:
Quantity of substanceVSAdaptability or versatility

Solution Approach 1:

The invention changes physical parameters (plasma power, gas flow rates, temperature, pressure) rather than relying on complex chemical solutions. By adjusting these parameters, the same plasma-based system can adapt to different matrix compositions and extract various metallic species efficiently, resolving the adaptability issue of hydrometallurgy

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces the complex chemical system of hydrometallurgy (multiple chemical reagents, solutionization steps, purification chemicals) with a plasma-based physical-chemical process. The plasma provides both thermal energy for evaporation and reactive species for selective extraction, simplifying the overall process while maintaining extraction effectiveness

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Adaptability or versatility

If pyrometallurgy is used to extract metals from electronic waste, then the process can be adapted to variable composition, but energy consumption is high and purity consistency is not guaranteed

Engineering Contradiction:
Improveadaptability to matrix compositionVSAvoidenergy consumption
Core Design Contradiction:
Adaptability or versatilityVSUse of energy by moving object

Solution Approach 1:

Instead of applying extreme high-temperature pyrometallurgical processing to all materials, the plasma process applies targeted energy only where needed for selective extraction. The plasma can be tuned to provide just enough energy to vaporize and extract specific metallic species at controlled rates, reducing overall energy consumption while maintaining adaptability

Inventive Principle:
Principle #16Partial or excessive action

Solution Approach 2:

The invention incorporates real-time monitoring of extraction conditions and adjusts plasma parameters dynamically to maintain consistent purity levels. This feedback control ensures that even with variable matrix composition, the extraction process maintains stable performance and product quality, addressing the purity consistency issue

Inventive Principle:
Principle #23Feedback

3Manufacturing precision

If plasma extraction is used to selectively extract metallic species, then high purity and adaptability are achieved, but real-time monitoring and parameter adjustment are required

Engineering Contradiction:
Improveextraction purityVSAvoidparameter control system
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The system uses real-time monitoring of plasma characteristics (emission spectra, power consumption, gas flow) to automatically adjust extraction parameters. This closed-loop feedback control achieves high extraction purity by continuously optimizing conditions while managing system complexity through automation rather than manual intervention

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the efficient and selective extraction of metallic species, including rare earths, from matrices of any composition, achieving high purity and allowing for sequential recovery of multiple species without redesigning the system, thus addressing the limitations of existing technologies.

Implementation Method 1

injecting a plasma in an extraction chamber by means of a plasma torch

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

formation of molecules, at the surface of the matrix, from chemical elements contained in the matrix and in the plasma

Methodology Applied
Scientific EffectChemical reactions: Chemical Bonding

Implementation Method 3

evaporation of said molecules from the matrix

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 4

The plasma is caused to act on the matrix for a predetermined period of time

Methodology Applied
Scientific EffectThermal energy: Heating

Implementation Method 5

destruction of some molecules and excitation of chemical elements contained in the molecules and extracted from the matrix

Methodology Applied
Scientific EffectPlasma excitation: Ionisation

Implementation Method 6

continuously monitoring the excited elements extracted from the matrix and contained in the plasma by optical emission spectroscopy

Methodology Applied
Scientific EffectOptical emission spectroscopy: Luminescence

Implementation Method 7

collection of said molecules comprising said desired species by deposition onto the surface of the plate

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Data Source

PatentUS11692239B2Process and system for plasma-induced selective extraction and recovery of species from a matrix
Publication Date: 2023.07.04 CENT NAT DE LA RECH SCI (C N R S)
  • US11692239B2 patent drawing
  • US11692239B2 patent drawing
  • US11692239B2 patent drawing

AI summary

The invention relates to a process for selectively and continuously extracting a series of desired species from a matrix, comprising the steps of:—injecting a plasma (310) in an extraction chamber by means of a plasma torch,—continuously monitoring (320) the excited elements extracted from the matrix and contained in the plasma by optical emission spectroscopy, and for each species of the series,—setting a distance (330) between the support and the plasma torch, and the composition of the injected plasma as a function of the monitored excited elements so that only one desired species of the series of species is being extracted from the matrix under molecular form, and—providing (400) a plate in the extraction chamber, exterior to the plasma, causing collection of molecules comprising said desired species by deposition onto the surface of the plate.